Výsledky vyhledávání - "Travis T. Lekich"

H2 addition to (Me4PCP)Ir(CO): studies of the isomerization mechanism

Autor: Sarina M. Bellows, Travis T. Lekich, J. Brannon Gary, Thomas R. Cundari, D. Michael Heinekey, Louise M. Guard

Publikováno v: Dalton Transactions. 47:16119-16125

Reduced steric demand of the Me4PCP pincer ligand (PCP = κ3-C6H4-1,3-[CH2PR2]2, R = Me), allows for a more open metal center. This is evident through structure and reactivity comparisons between (Me4PCP)Ir derivatives and other (R4PCP)Ir complexes (

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d592cf9fa70c93edba6792d4b6de16d3
https://doi.org/10.1039/c8dt02861c

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An Improved Synthesis of Me4PCP and DMPE

Autor: Ryan K. Burdick, Phoebe G. Askelson, Travis T. Lekich, D. Michael Heinekey

Publikováno v: Organometallics. 37:211-213

We present a new synthetic method for the bis(dimethyl)phosphines Me4PCP (C6H4-2,6-(CH2P(CH3)2)2) and DMPE ((CH3)2PCH2CH2P(CH3)2) that starts from an aminophosphine, Et2NPMe2. Two equivalents of Et2NPMe2 react with the corresponding bis(alkyl bromide

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::64cdccf6e9fc82ec265e7a3ea603450e
https://doi.org/10.1021/acs.organomet.7b00780

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Autor: Travis T, Lekich, J Brannon, Gary, Sarina M, Bellows, Thomas R, Cundari, Louise M, Guard, D Michael, Heinekey

Publikováno v: Dalton transactions (Cambridge, England : 2003). 47(45)

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::c654a3700114b438ad08c4f8fef06ad7
https://pubmed.ncbi.nlm.nih.gov/30377682

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Synthesis of Unsupported d1–dx Oxido-Bridged Heterobimetallic Complexes Containing VIV: A New Direction for Metal-to-Metal Charge Transfer

Autor: Walter W. Weare, Roger D. Sommer, Xinyuan Wu, Travis T. Lekich, Tao Huang

Publikováno v: Inorganic Chemistry. 54:5322-5328

Heterobimetallic complexes composed only of first-row transition metals [(TMTAA)V(IV)═O→M(II)Py5Me2](OTf)2 (TMTAA = 7,16-dihydro-6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraazacyclotetradecine; Py5Me2 = 2,6-bis(1,1-bis(2-pyridyl)ethyl)pyridin

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3b67a7398ac225c237b85b47b322b792
https://doi.org/10.1021/acs.inorgchem.5b00370

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