Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Travis J. Hebden"'
Publikováno v:
Organometallics. 36:3104-3109
A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of (tBuPOCOP)Co(CO) with H2, acids, and carbon monoxide has been compared to that of the previously reported Rh a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0903fc149ce96a92ff0e8deac6428d9f
https://doi.org/10.1021/acs.organomet.7b00434
https://doi.org/10.1021/acs.organomet.7b00434
Autor:
Werner Kaminsky, Travis J. Hebden, D. Michael Heinekey, Dmitry G. Gusev, Karen I. Goldberg, Anthony J. St. John
Publikováno v:
Angewandte Chemie International Edition. 50:1873-1876
Ammonia borane (AB) is an attractive candidate for the chemical storage of hydrogen. Recently, our research group reported that the complex [(pocop)IrH2] (pocop= k -C6H31,3-[OP(tBu)2]2) has facilitated the rapid release of H2 from AB under mild condi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2f433bec14b10708102d6ae8b8e2efce
https://doi.org/10.1002/anie.201005281
https://doi.org/10.1002/anie.201005281
Autor:
Melanie C. Denney, D. Michael Heinekey, Vincent Pons, Karen I. Goldberg, Paula M. B. Piccoli, Arthur J. Schultz, Travis J. Hebden, Thomas F. Koetzle, Werner Kaminsky
Publikováno v:
Journal of the American Chemical Society. 130:10812-10820
Reaction of NaBH4 with (tBuPOCOP)IrHCl affords the previously reported complex (tBuPOCOP)IrH2(BH3) (1) (tBuPOCOP = kappa(3)-C6H3-1,3-[OP(tBu)2]2). The structure of 1 determined from neutron diffraction data contains a B-H sigma-bond to iridium with a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb7ad50aae20dc43c006cf376946462c
https://doi.org/10.1021/ja801898m
https://doi.org/10.1021/ja801898m
Autor:
Travis J. Hebden, D. Michael Heinekey, Karsten Krogh-Jespersen, Thomas J. Emge, Karen I. Goldberg, Xiawei Zhang, Alan S. Goldman
Publikováno v:
Inorganic chemistry. 49(4)
The iridium pincer complexes (PCP)IrH(4) (1; PCP = [kappa(3)-1,3-(CH(2)P(t)Bu(2))(2)C(6)H(3)]) and (POCOP)IrH(4) (2; POCOP = [kappa(3)-1,3-(OP(t)Bu(2))(2)C(6)H(3)]) have proven to be effective catalyst precursors for dehydrogenation of alkanes. The c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cf12e4cbc0c0a653c6a51919ec480a90
https://pubmed.ncbi.nlm.nih.gov/20095648
https://pubmed.ncbi.nlm.nih.gov/20095648
Publikováno v:
Journal of the American Chemical Society. 128(37)
In the presence of an iridium pincer complex, dehydrogenation of ammonia borane (H3NBH3) occurs rapidly at room temperature in tetrahydrofuran to generate 1.0 equivalent of H2 and [NH2BH2]5. A metal borohydride complex has been isolated as a dormant
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::956427702702ce9b2182d61f88107a30
https://pubmed.ncbi.nlm.nih.gov/16967937
https://pubmed.ncbi.nlm.nih.gov/16967937
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (32)
A new ligand conceptually creates two sites reminiscent of beta-diketiminates, and upon deprotonation the salts exist in oligomeric forms with potassium ions linking multiple ligands.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a5231a5013311ff5a7d403dd47d1dad0
https://pubmed.ncbi.nlm.nih.gov/16896444
https://pubmed.ncbi.nlm.nih.gov/16896444
Publikováno v:
Chemical Communications. 48:1851
(t-BuPOCOP)MoI(2) (1; t-BuPOCOP = C(6)H(3)-1,3-[OP(t-Bu)(2)](2)) has been synthesized from MoI(3)(THF)(3). Upon reduction of 1 with Na/Hg under dinitrogen molecular nitrogen is cleaved to form [(t-BuPOCOP)Mo(I)(N)](-). The origin of the N atom was co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9f999a211a2606c5b1db40d7adf1ef3
https://doi.org/10.1039/c2cc17634c
https://doi.org/10.1039/c2cc17634c
Publikováno v:
Dalton Transactions: An International Journal of Inorganic Chemistry; Aug2006, Vol. 2006 Issue 32, p3855-3857, 3p