Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Trang Le Husebo"'
Autor:
Joseph Merola, Trang Le Husebo
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 4, Pp m122-m123 (2014)
The title compound, [Ir2H2O(C3H9P)6](BF4)2·2H2O, was isolated from the reaction between [Ir(COD)(PMe3)3]BF4 and H2 in water (COD is cycloocta-1,5-diene). The asymmetric unit consists of one IrIII atom bonded to three PMe3 groups, one hydride ligand
Externí odkaz:
https://doaj.org/article/f9d256a4d1664ec79b9f5cf459ecda0e
Publikováno v:
Inorganica Chimica Acta. 390:33-36
Two unusual dinuclear iridium complexes are reported with unsupported bridging chloride ligands. The first comes from an aqueous solution of H 2 ClIr(PMe 3 ) 3 by the addition of KPF 6 . The second is formed in the reaction between H(C 6 H 5 )ClIr(PM
Publikováno v:
Organometallics. 31:3920-3929
A series of Ir(H)2(PMe3)3X compounds where X = various anionic ligands has been synthesized. The most studied of this group with X = Cl has been characterized fully, including by X-ray crystallography. For X = Cl, PhCO2–, dissolution in water resul
Autor:
Ilia M Guzei, Cheryl J. Bourgeois, and Lev. N. Zakharov, Trang Le Husebo, Louise M. Liable-Sands, Arnold L. Rheingold, Russell P. Hughes, Jeremy M. Smith
Publikováno v:
Organometallics. 24:6431-6439
While reaction of n-C3F7I with CpRh(PMe3)(CO) gives the expected product of oxidative addition, CpRh(PMe3)(nC3F7)(I), the analogous reaction of iso-C3F7I affords a mixture of CpRh(PMe3)(CF(CF3)2)(I) and the perfluoroacyl complex CpRh(PMe3)(COCF(CF3)2
Autor:
Joseph, Merola, Trang Le, Husebo
Publikováno v:
Acta Crystallographica Section E: Structure Reports
The title compound, [Ir2H2O(C3H9P)6](BF4)2·2H2O, was isolated from the reaction between [Ir(COD)(PMe3)3]BF4 and H2 in water (COD is cyclo-octa-1,5-diene). The asymmetric unit consists of one Ir(III) atom bonded to three PMe3 groups, one hydride liga
Autor:
Russell P. Hughes, Louise M. Liable-Sands, Bradley J. Holliday, Arnold L. Rheingold, Trang Le Husebo
Publikováno v:
Journal of Organometallic Chemistry. 548:109-112
Reactions of [Co( η 5 -C 5 H 5 )(CO) 2 ] with perfluoro- n -propyl iodide proceeds by selective fluoroalkylation at the metal center to give [Co( η 5 -C 5 H 5 )(CO)(R F )] ( 3 ; R F = CF 2 CF 2 CF 3 ). Treatment of 3 with excess PMe 3 affords catio
Publikováno v:
Inorganic Chemistry Communications. 1:197-199
[η5-C5H4(CH2CH2(CF2)9CF3]Rh(CO)L (L = CO (1) or P[CH2CH2(CF2)5CF3]3 (2)) and Cl2Ni{P[CH2CH2(CF2)5CF3]3}2 (3) were prepared and characterized. The fluorous partition coefficients ( P FBS = C Fluorous Phase C Other phase ) of 1 (PFBS = 0.8), 2 (PFBS =
Autor:
Trang Le Husebo, and Louise M. Liable-Sands, Arnold L. Rheingold, Glenn P. A. Yap, Russell P. Hughes,† and
Publikováno v:
Organometallics. 16:5-7
Reactions of [Rh(η5-C5H5)(CO)2] with isomeric primary and secondary fluoroalkyl iodides proceed by selective fluoroalkylation at the metal center to give [Rh(η5-C5H5)(CO)(RF)I], and treatment of th...
Publikováno v:
Aqueous Organometallic Chemistry and Catalysis ISBN: 9789401041584
Moving catalytic processes from organic solvents into water may have significant advantages: not only is water more environmentally benign, but product separation may be accomplished more readily. The bulk of the activity directed toward developing w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ef1cdd3cb3043ae3dc62ac2f96e901da
https://doi.org/10.1007/978-94-011-0355-8_4
https://doi.org/10.1007/978-94-011-0355-8_4
Autor:
Ilia A. Guzei, Susan M. Maddock, Russell P. Hughes, Arnold L. Rheingold and, and Trang Le Husebo
Publikováno v:
Journal of the American Chemical Society. 119:10231-10232