Výsledky vyhledávání - "Toshiro Takao"

Akademický článek

Synthesis of a diruthenium μ-η⁴ -α-diimine complex via dehydrogenative coupling of cyclic amines and its role in dehydrogenative oxidation of pyrrolidine.

Autor: Toshiro Takao, Ryuichi Shimogawa, Ryosuke Fujita, Shu Egawa

Publikováno v: Dalton Transactions: An International Journal of Inorganic Chemistry; 12/7/2023, Vol. 52 Issue 45, p16737-16753, 17p

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Syntheses and Properties of Triruthenium Polyhydrido Complexes Composed of 1,2,4-tri-tert-butylcyclopentadienyl and p-Cymene Ruthenium Units

Autor: Ryuichi Shimogawa, Hidenori Suzuki, Toshiro Takao

Publikováno v: Organometallics. 40:1303-1313

Mixed-ligand triruthenium hydrido complexes composed of [Cp‡Ru] (Cp‡ = 1,2,4-tri-tert-butylcyclopentadienyl) and [(p-cymene)Ru] fragments, [(Cp‡Ru)2{(p-cymene)Ru}(μ-H)3(μ3-H)] (3a) and [(Cp‡Ru){(p-...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6a18d3c768fea241d420a0596c60e9bc
https://doi.org/10.1021/acs.organomet.1c00094

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Intramolecular Nitrene Transfer via the C≡N Bond Cleavage of Acetonitrile to a μ3-Alkylidyne Ligand on a Cationic Triruthenium Plane

Autor: Toshiro Takao, Atsushi Tahara, Yusuke Takahashi

Publikováno v: Organometallics. 39:2888-2899

The μ3-η2-iminoacyl-μ3-hexylidyne complex, [(Cp*Ru)3(μ3-CC5H11)(μ3-η2-HN═CMe)(μ-H)] (2a) (Cp* = η5-C5Me5), was prepared by the reaction of the μ3-η2:η2(⊥)-hexyne complex, [{Cp*Ru(μ-H)}3(μ3-η2:η2-nB...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f1fc8ab383bd3e5e59a8932f96c99a9
https://doi.org/10.1021/acs.organomet.0c00393

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Reaction of a Triruthenium μ3-Borylene Complex with Benzonitrile: Formation of a μ3-η3-BCN Ring on a Cationic Ru3 Plane via Photo-Induced Intramolecular Borylene Transfer

Autor: Takeshi Kaneko, Toshiro Takao

Publikováno v: Organometallics. 39:593-604

A μ3-η2(||)-iminobenzoyl complex supported by a μ3-borylene ligand, [(Cp*Ru)3(μ3-BH)(μ3-η2-PhCNH)(μ-H)2] (5a; Cp* = η5-C5Me5), was synthesized as an equilibrated mixture with its isomer, 5b, by the reaction of a μ3-borylene complex, [{Cp*Ru(

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4013ea32808739d37ecf43e5e0722d64
https://doi.org/10.1021/acs.organomet.9b00831

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Selective Synthesis of a Triruthenium Pentahydrido Complex with Mixed-Cp Ligands (C5tBu3H2 and C5Me5) and Its Transformation into Face-Capping Benzene Complexes: Fluxionality of a Face-Capping Benzene Ligand Induced by Oxidation

Autor: Toshiro Takao, Hidenori Suzuki, Ryuichi Shimogawa, Yohei Tsurumaki

Publikováno v: Organometallics. 38:3824-3833

A mixed-ligand triruthenium μ-chloro complex, [(Cp‡Ru)(Cp*Ru)2(μ-H)4(μ-Cl)] (7; Cp‡ = η5-C5tBu3H2, Cp* = η5-C5Me5) was synthesized by the reaction of [{Cp*Ru(μ-H)2}2] (5a) with [{Cp‡Ru(μ-Cl)}2] (6). The subsequent treatment of 7 with 2-p

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0f1f01c1c296f31823fab21b61ea0673
https://doi.org/10.1021/acs.organomet.9b00503

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Formation of a μ3-Acetylide on a Ru3 Cluster via Coupling of μ-Methylene with Isocyanide Accompanied by Elimination of Amine: A Model of Hydrogen-Assisted C–C Bond Formation on a Metal Surface

Autor: Hiroki Chikamori, Toshiro Takao

Publikováno v: Organometallics. 38:2705-2709

A μ3-methylidyne complex of ruthenium, [(Cp*Ru)3(μ3-CH)(μ-H)2(μ3-S)] (3; Cp* = (C5Me5)Ru), was synthesized by the reaction of [{Cp*Ru(μ-H)}3(μ3-H)2] (1) with thioanisole. Complex 3 isomerized to a ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c2ab57aa368362b6ff7e10a6c07b8bc1
https://doi.org/10.1021/acs.organomet.9b00301

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