Zobrazeno 1 - 10
of 124
pro vyhledávání: '"Toshinobu Korenaga"'
Autor:
Hiroki Mandai, Kazuki Fujii, Hiroshi Yasuhara, Kenko Abe, Koichi Mitsudo, Toshinobu Korenaga, Seiji Suga
Publikováno v:
Nature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
Nucleophilic catalysts are widely used for acyl transfer reactions, but chiral variants can be difficult to design or synthesise. Here, the authors report catalysts with chirality imparted from a binaphtyl moiety with tert-alcohol unit that show both
Externí odkaz:
https://doaj.org/article/5e7f35966c0a4cdb94c85844b7113628
Autor:
Masanori Shigeno, Kazutoshi Hayashi, Toshinobu Korenaga, Kanako Nozawa-Kumada, Yoshinori Kondo
Publikováno v:
Organic Chemistry Frontiers. 9:3656-3663
The organic superbase t-Bu-P4 catalyzes the demethylation reactions of methoxyarenes in the presence of alkanethiol and hexamethyldisilazane.
Autor:
Masanori Shigeno, Akihisa Kajima, Eito Toyama, Toshinobu Korenaga, Hiroyuki Yamakoshi, Kanako Nozawa‐Kumada, Yoshinori Kondo
Publikováno v:
Chemistry – A European Journal. 29
We demonstrate that lithium hexamethyldisilazide (LiHMDS) acts as an effective base for deprotonative coupling reactions of toluenes with ketones to afford stilbenes. Various functionalities (halogen, OCF3, amide, Me, aryl, alkenyl, alkynyl, SMe, and
Autor:
Yoshikazu Horino, Toshinobu Korenaga
Publikováno v:
The Chemical Record. 21:3911-3924
π-Allylpalladium complexes can not only serve as electrophilic allylating agents for a broad range of nucleophiles, but also nucleophilic allylating agents for electrophiles depending on their electronic environments. In contrast to these typical re
Publikováno v:
Chemical Science
The dynamic parallel kinetic resolution (DPKR) of an α-ferrocenyl cation intermediate under the influence of a chiral conjugate base of a chiral phosphoric acid catalyst has been demonstrated in an SN1 type substitution reaction of a racemic ferroce
Publikováno v:
Advanced Synthesis & Catalysis. 363:3592-3599
Publikováno v:
ChemCatChem. 12:6059-6066
Autor:
Yoshikazu Horino, Toshinobu Korenaga
Publikováno v:
The Chemical Record. 22
Publikováno v:
Natural Product Communications. 14(9):1-9
10-Imidazolylbornane-2-one bearing a sterically crowded spirocyclic substituent at the C-3 position was prepared from d-camphor through the procedure involving the formation of 10-bromobornane-2-thiones or 10-iodobornane-2-thiones and the subsequent
Autor:
Mariko Suzuki, Yuji Takikawa, Toshinobu Korenaga, Shigenobu Aoyagi, Kazuaki Shimada, Kohei Yahaba
Publikováno v:
Natural Product Communications. 14(6):1-13
Synthesis of phenanthroindolizidine core was efficiently achieved through a pathway involving hetero Diels-Alder reaction of α-allenylchalcogenoketenes, generated in situ by thermal [3,3] sigmatropic rearrangement of alkynyl propargyl sulfides or se