Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Toshikazu Tsuchiya"'
Autor:
Toshikazu Tsuchiya, Manabu Takeuchi
Publikováno v:
NIP & Digital Fabrication Conference. 20:534-537
Publikováno v:
Journal of the Mass Spectrometry Society of Japan. 31:51-54
The amount of kinetic energy released in the metastable ion reaction M+ → [M-NO]+ + NO· has been determined for several substituted nitrobenzenes by scanning the electric sector voltage of a double focusing mass spectrometer. The order of the amou
Publikováno v:
Journal of the Mass Spectrometry Society of Japan. 34:99-105
Fragmentation process of 1,2-([1]), 1,3-([2]) and 1,4-([3]) benzenedicarboxylic acid dimethyl esters by electron impact has been investigated by using deuterium labelling techniques, ion kinetic energy and mass analyzed ion kinetic energy spectra. Th
Publikováno v:
Journal of the Mass Spectrometry Society of Japan. 29:365-370
The formation of an [M+1]+ ion and the fragmentation of isopropyl o-toluate have been further investigated by measuring the mass spectrum of CD3C6H4COOC3H7(d3). The hydrogen atom, which is involved in the [M+1]+ ion formation, originates mainly from
Publikováno v:
Organic Mass Spectrometry. 19:326-329
The substituent effect on the single and double hydrogen atom transfer reactions in para-substituted benzoic acid isobutyl esters has been investigated by electron impact mass spectrometry. Electron-donating substituents favour formation of the [MC4H
Publikováno v:
Chemistry Letters. 6:203-206
The average translational energy of ions has been readily measured by applying a variable retarding potential of negative voltage to the repeller electrode. The measured value of the methyl ion from acetonitrile at the threshold is in fair agreement
Publikováno v:
Bulletin of the Chemical Society of Japan. 50:3103-3106
The mass spectra of 1-alkenes ranging from C5 to C10 were measured at temperatures of the ion source 120–250 °C. Fragmentation M+\oversetm28→(M–28)+ and M+\oversetm28→(M–29)+, where m28 and m29 denote the metastable peaks of the fragmentat
Publikováno v:
Organic Mass Spectrometry. 15:609-612
The temperature effect on the single and double hydrogen atom transfer reactions in o-, m- and p-toluic acid n-butyl esters and isobutyl esters has been investigated. For the meta and para isomers, the abundance of the m/z 137 ion [C8H9O2]+ generated
Publikováno v:
Organic Mass Spectrometry. 14:499-502
Single and double hydrogen atom transfers in reactions (1) and (2) in the mass spectra of ethyl benzoate, isopropyl benzoate, and isobutyl benzoate have been investigated with reference to the ortho effect: (1) [C6H5CO2R]+⋅ [C6H5CO2H]+⋅ (m/z 122)
Autor:
Susumu Tajima, Toshikazu Tsuchiya
Publikováno v:
Organic Mass Spectrometry. 9:265-273
The structure and decomposition of the [C7H7]+ ions produced by electron-impact from o-, m- and p-chlorotoluene, o-, m- and p-bromotoluence, and p-iodotoluence, have been investigated. By determining the relative abundance of normal and metastable io