Zobrazeno 1 - 10
of 177
pro vyhledávání: '"Tomohisa Takita"'
Autor:
Tomohisa Takita, Yoshiaki Takahashi, Nobuhiro Ito, Tomio Takeuchi, Hitoshi Nakayama, Kumi Ichikawa, Keiki Katagiri, Toshiaki Miyake
Publikováno v:
Tetrahedron Letters. 42:1053-1056
Optically pure 1 d - chiro -inositol (DCI) has been synthesized from optically inactive myo -inositol practically in four steps. The crystalline nature of most intermediates and the utilization of inexpensive reagents facilitate the economical mass p
Publikováno v:
ChemInform. 22
Intramolecular cyclization of the cis -epoxy-alcohol ( 6 ) with KOH in aq.DMSO provided predominantly the oxetane compound ( 7 ), which on oxidation followed by Baeyer-Villiger reaction gave 1-O- acetyl-D-erythrooxetanoses.
Publikováno v:
ChemInform. 23
Publikováno v:
ChemInform. 24
Treatment of 2,2-bis(benzyloxymethyl)cyclopropanecarboxylic acid 8 with ethyl chloroformate and sodium azide followed by thermolysis of the resulting keto azide 9 at 80 °C provided the corresponding isocyanate 10, which was then converted into 2,2-b
Publikováno v:
ChemInform. 23
(1 R 2 R ,3 S )-1-Amino-2,3-bishydroxymethylcyclobutane derivatives ( 14, 15 ) have been synthesized enantioselectively by [2+3] formation of a cyclopentane ring from (−)-dimenthyl succinate and 3-chloro-2-(chloromethyl)-1-propene and the subsequen
Autor:
Tomohisa Takita, Shosuke Yamamura, Kumiko Nakayama, Takao Izawa, Kuniki Kato, Shigeru Nishiyama
Publikováno v:
ChemInform. 24
The arabino-lactone triflate 4 reacts with K2CO3 in MeOH to give the oxetane ester 5 and the tetrahydrofuran ester 6 in a ratio dependent upon the reaction temperature.
Publikováno v:
ChemInform. 24
Publikováno v:
Tetrahedron. 48:1573-1580
(1 R 2 R ,3 S )-1-Amino-2,3-bishydroxymethylcyclobutane derivatives ( 14, 15 ) have been synthesized enantioselectively by [2+3] formation of a cyclopentane ring from (−)-dimenthyl succinate and 3-chloro-2-(chloromethyl)-1-propene and the subsequen
Publikováno v:
Nucleosides and Nucleotides. 11:417-436
Upon treatment of 1-O-acetyl-D-erythrooxetanoses (17a,b and 26) with trimethylsilyl N-benzoyladenine or allyltrimethylsilane in the presence of SnCl4, the ring expanded products (18, 19 and 29) or the acyclic compounds (27 and 28) were obtained. The
Synthesis of carbocyclic nucleosides: synthesis of (±)-2,2-bis(hydroxymethyl)cyclopropyl nucleosides
Publikováno v:
J. Chem. Soc., Perkin Trans. 1. :2519-2525
Treatment of 2,2-bis(benzyloxymethyl)cyclopropanecarboxylic acid 8 with ethyl chloroformate and sodium azide followed by thermolysis of the resulting keto azide 9 at 80 °C provided the corresponding isocyanate 10, which was then converted into 2,2-b