Zobrazeno 1 - 10
of 85
pro vyhledávání: '"Tomoharu Ama"'
Publikováno v:
Acta Crystallographica Section E, Vol 66, Iss 4, Pp m483-m484 (2010)
In the title compound, [CaCo3(C4H5NO4)3(OH)3O(H2O)5]·2.54H2O, the Co atom is octahedrally coordinated by one iminodiacetate (ida) dianion as a facial O,N,O′-tridentate ligand, two μ3-OH groups and one μ3-O ligand, forming an partial Co3O4 cubane
Externí odkaz:
https://doaj.org/article/7c50cde870df4c8682727b134e2aec81
Autor:
Tomoko Hashimoto, Toshiaki Yonemura, Tomoharu Ama, Mayumi Hasegawa, Tamami Ikenoue, Hiroshi Kawaguchi
Publikováno v:
Inorganic Chemistry Communications. 9:183-186
The reaction of the molybdenum–dinitrosyl complexes with PPh3, using 2-pyrimidinethiolate (pymt) or 2-pyridinethiolate (pyt) as a thiolate ligand, was found to produce a dinuclear complex [{(ON)MoL2}2(μ-OH)2] (1) (L = pymt or pyt) and Ph3PO. In ad
Autor:
Hiroshi Kawaguchi, Md. Monzur Rashid, Ashok Kumar Sarker, Toshiaki Yonemura, Hideyuki Miyakawa, Takaji Yasui, Tomoharu Ama
Publikováno v:
Bulletin of the Chemical Society of Japan. 74:2327-2333
A trinuclear cobalt(III) complex, [Co3(L-his)3(μ-OH)3(μ3-O)]ClO4·H2O (L-Hhis: L-histidine), containing an incomplete cubane Co3O4 core was isolated and the structure was compared with [Co3(edma)3(μ-OH)3(μ3-O)]+ (Hedma: NH2CH2CH2NHCH2COOH) isomer
Autor:
Divna M. Ristanovic, Dušan J. Radanović, Svetlana K Janićijević, Nenad S. Drašković, Hiroshi Kawaguchi, Tomoharu Ama
Publikováno v:
Bulletin of the Chemical Society of Japan. 74:701-706
The hexadentate complex Mg[Ni(1,3-pdta)]•H2O (1,3-pdta = 1,3-propanediaminetetraacetate ion) was prepared and its structure established by X-ray crystallography. The complex salt crystallizes in the space group Pnna (# 52) of the orthorhombic cryst
Autor:
Dejan M. Gurešić, Divna M. Ristanovic, Dušanka Radanović, Dušan J. Radanović, Hiroshi Kawaguchi, Tomoharu Ama
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:2283-2288
The hexadentate complex trans(O5)-Mg[Cu(ed3ap)]·8H2O (1) (ed3ap = ethylenediamine-N,N,N′-triacetate-N′-3-propionate (4-) ion) has been prepared and its structure established by X-ray crystallography. The complex crystallizes in space group Pna21
Publikováno v:
Coordination Chemistry Reviews. 198:101-116
The modeling study of the photosynthetic water oxidation center has been extended to the cobalt(III) complexes with incomplete or complete cubane core. In the preparation of the [Co3(NNO)3(μ-OH)3(μ3-O)]+ complexes from [Co(NNO)(H2O)3]2+
Autor:
Ken-ichi Okamoto, Toshiaki Yonemura, Kimi Shibuya, Tomoharu Ama, Hiroshi Kawaguchi, Jinsai Hidaka, Takaji Yasui
Publikováno v:
Inorganic Chemistry. 38:3244-3247
A [Co(N)2(O)2(S)2]-type complex containing two coordinated thioether groups, trans(O)-[Co(edtda)(en)]+ (edtda = ethylenedithiodiacetate; en = ethylenediamine), has been prepared which was spontaneously resolved. The photodecarboxylation reaction of t
Autor:
Takaji Yasui, Hiroshi Kawaguchi, Ken-ichi Okamoto, Toshiaki Yonemura, Zhi-Ping Bai, Jinsai Hidaka, Tomoharu Ama
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2151-2158
The trans(S)-[Co(N)4(S)2]-type mononuclear complexes [Co(L)2(en)]+ or – (L = 2-aminoethanethiolate (aet) 1, L-cysteinate (L-cys) 3 or D-penicillaminate (3-sulfanyl-D-valinate) (D-pen) 5) were newly prepared by the reaction of trans-[CoCl2(en)2]+ wi
Publikováno v:
Bulletin of the Chemical Society of Japan. 71:1605-1614
The preparation and resolution of the two hexadentate Co(III) complexes containing unsymmetrical edta-type ligands, [Co(ed3ap)]− (A) and [Co(u-eddadp)]− (B) (ed3ap = ethylenediamine-N,N,N′-triacetate-N′-3-propionate ion; u-eddadp = ethylenedi
Publikováno v:
Bulletin of the Chemical Society of Japan. 79:1063-1065
Two isomers of N-(2-pyridylmethyl)glycinatocobalt(III) complexes containing incomplete cubane Co3O4 cores, [Co3(pg)3(μ3-O)(μ-OH)3]+, were isolated and their structures were determined by the X-ray ...