Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Tommy Hawkins"'
Publikováno v:
Journal of Chemical Crystallography. 37:15-23
A new class of energetic ionic liquids based upon 1-amino-3-alkyl-1,2,3-triazolium nitrates (alkyl = methyl, ethyl, n-propyl, 2-propenyl, and n-butyl) has been synthesized and characterized by vibrational spectra, multinuclear NMR, elemental as well
Publikováno v:
Propellants, Explosives, Pyrotechnics. 31:196-204
The synthesis, characterization, theoretical calculations, and safety studies of energetic salts based on 1,2-bis(oxyamino)ethane, (H2NOCH2CH2ONH2), were carried out. The salts were characterized by vibrational (infrared, Raman), multinuclear NMR stu
Publikováno v:
Propellants, Explosives, Pyrotechnics. 30:329-337
Reactions using the high nitrogen heterocycle 3,4,5-triamino-1,2,4-triazole (guanazine) with strong acids (HN03, HCl04, and "HN(N02)2") resulted in a family of highly stable salts. All of the salts were characterized using spectroscopic as well as si
Publikováno v:
Propellants, Explosives, Pyrotechnics. 30:156-163
The synthesis and characterization of 1 ,5-diamino- 1,2,3 ,4-tetrazolium perchlorate were carried out. Experimental evidence strongly supports the protonation of a nitrogen atom of the tetrazole ring, including the structure observed in a single crys
Publikováno v:
Energy & Fuels. 19:279-284
Although innumerable different ionic liquids are possible, even basic physical-property data, such as the density and melting point, exist only for relatively few. Derivation of melting point quantitative structure−property relationships (QSPRs) fo
Autor:
Gregory Drake, Tommy Hawkins, Adam Brand, Leslie Hall, Milton Mckay, Ashwani Vij, Ismail Ismail
Publikováno v:
Propellants, Explosives, Pyrotechnics. 28:174-180
The synthesis of three new families of heterocyclic-based salts was undertaken and accomplished. Three triazole systems, 1H-1,2,4-triazole, 4-amino-1,2,4-triazole, and 1H-1,2,3-triazole, were used as proton bases with nitric (HNO3), perchloric (HClO4
Autor:
Steven F. Son, Preston A. Beasley, Mark Pfiel, Steven P. Kelley, Jerry A. Boatz, Tommy Hawkins, Robin D. Rogers, Brandon W. McMahon, Stefan Schneider, Jesus Paulo L. Perez, Scott L. Anderson, Parker D. McCrary
Publikováno v:
Physical chemistry chemical physics : PCCP. 14(38)
The passivation and stability of suspensions of titanium nanoparticles in azolium azolate ionic liquids can be tuned by introducing metal specific binding sites in the azolate anion.
Autor:
Steven F. Son, Robin D. Rogers, Tommy Hawkins, Preston A. Beasley, Jerry A. Boatz, Brandon W. McMahon, O. Andreea Cojocaru, Jesus Paulo L. Perez, Stefan Schneider, Mark A. Pfeil, Scott L. Anderson, Parker D. McCrary
Publikováno v:
Chemical communications (Cambridge, England). 48(36)
Boron nanoparticles prepared by milling in the presence of a hypergolic energetic ionic liquid (EIL) are suspendable in the EIL and the EIL retains hypergolicity leading to the ignition of the boron. This approach allows for incorporation of a variet
Autor:
Tommy Hawkins, Jacob W. Petrich, Daniel W. Armstrong, Mark S. Gordon, Philip J. Carlson, Sayantan Bose
Publikováno v:
The journal of physical chemistry. B. 116(1)
An investigation of the structure and dynamics of the high-energy ionic liquid, 1-hydroxyethyl-4-amino-1,2,4-triazolium nitrate (HEATN), was undertaken. Both experimental and computational methods were employed to understand the fundamental propertie
Autor:
Stefan Schneider, Tommy Hawkins, Michael Rosander, Jeffrey Mills, Ghanshyam L. Vaghjiani, Steven D. Chambreau
Publikováno v:
Inorganic chemistry. 47(13)
Several imidazolium-based ionic liquid azides with saturated and unsaturated side chains were prepared, and their physical and structural properties were investigated. The reactivity of these new as well as some previously reported ionic liquid azide