A calix[4]arene with acylguanidine units as an efficient catalyst for phosphodiester bond cleavage in RNA and DNA model compounds

Autor: Alessandro Casnati, Roberta Cacciapaglia, Tommaso Folcarelli, Riccardo Salvio, Stefano Volpi

Publikováno v: Organic & biomolecular chemistry 17 (2019): 7482–7492. doi:10.1039/c9ob01141b
info:cnr-pdr/source/autori:Salvio, Riccardo; Volpi, Stefano; Folcarelli, Tommaso; Casnati, Alessandro; Cacciapaglia, Roberta/titolo:A calix[4]arene with acylguanidine units as an efficient catalyst for phosphodiester bond cleavage in RNA and DNA model compounds/doi:10.1039%2Fc9ob01141b/rivista:Organic & biomolecular chemistry/anno:2019/pagina_da:7482/pagina_a:7492/intervallo_pagine:7482–7492/volume:17

A calix[4]arene scaffold, blocked in the cone conformation and decorated at the upper rim with two acylguanidine units, effectively catalyzes the cleavage of phosphodiester bonds of HPNP and BNPP under neutral pH conditions. The catalyst performance

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https://publications.cnr.it/doc/408317