Crystal structure of {(but-3-en-1-yl)bis[(pyridin-2-yl)methyl]amine-κ3N,N′,N′′}dichloridocopper(II) diethyl ether hemisolvate

Autor: Katherine A. Bussey, Jennifer R. Connell, Annie R. McGlone, Margaret E. Mraz, Kayode D. Oshin, Tomislav Pintauer, Allen G. Oliver

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 3, Pp 309-311 (2015)

The five-coordinate CuII atom in the title complex [CuCl2(C16H19N3)]·0.5C4H10O, adopts a near-ideal square-pyramidal geometry (τ-5 = 0.01). The apical Cu—Cl distance is 0.2626 (6) Å longer than the basal Cu—Cl distance. Weak C—H...Cl interac

Externí odkaz: https://doaj.org/article/9480cb86b8764be68d68220832182a40

Bioinspired, Multidisciplinary, Iterative Catalyst Design Creates the Highest Performance Peroxidase Mimics and the Field of Sustainable Ultradilute Oxidation Catalysis (SUDOC)

Autor: Michael P. Hendrich, Genoa R. Warner, Gabrielle Pros, Yogesh Somasundar, Tomislav Pintauer, Matthew R. Mills, Kyle C. Jansen, Longzhu Q. Shen, Alexander D. Ryabov, Abigail E. Burton, Frederick S. vom Saal, Cindy Weng, Saborni Biswas, Julia A. Taylor, Evan Z. Kaaret, Terrence J. Collins

Publikováno v: ACS Catalysis. 9:7023-7037

Oxidation catalysts called NewTAMLs, macrocyclic complexes with TAML carbonamido-N donors replaced by more nucleophile-resistant binders, sulfonamido-N, for example, [Fe{4-NO2C6H3-1,2-(NCOCMe2NSO2)...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::48a4eeaf3ff35eca3521225a2c53459c
https://doi.org/10.1021/acscatal.9b01409

Synthesis, characterization, X-ray crystallography analysis, and catalytic activity of bis(2-pyridylmethyl)amine copper complexes containing coupled pendent olefinic arms in atom transfer radical addition (ATRA) reactions

Autor: Amy A. Sarjeant, Kayode D. Oshin, Annie R. Cavalier, Margaret E. Mraz, Tomislav Pintauer, Katherine A. Bussey

Publikováno v: Polyhedron. 114:256-267

The synthesis, characterization, and catalytic activity of bis(2-pyridylmethyl)amine (BPMA) copper complexes incorporating olefinic pendent arms are reported. Four copper(I) and four copper(II) complexes were synthesized employing four different coun

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0b887505ddaab53487273e1cf426c508
https://doi.org/10.1016/j.poly.2015.12.043

Stability and Reactivity of 1,3-Benzothiaphosphole: Metalation and Diels–Alder Chemistry

Autor: Erich Hellemann, Joshua C. Worch, Chakicherla Gayathri, Kevin J. T. Noonan, Tomislav Pintauer, Roberto R. Gil, Gabrielle Pros

Publikováno v: Organometallics. 34:5366-5373

The synthesis and functionalization of the parent 1,3-benzothiaphosphole is reported. The phosphole could not be isolated, but the compound could be manipulated in solution to produce several new phosphorus compounds. Metalation of the 2-position usi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f656ae8cd379edd6062964db324f8d4
https://doi.org/10.1021/acs.organomet.5b00583

Crystal structure of orthorhombic {bis[(pyridin-2-yl)methyl](3,5,5,5-tetrachloropentyl)amine-κ3N,N′,N′′}chloridocopper(II) perchlorate

Autor: Annie R. Cavalier, Sean Parkin, Katherine A. Bussey, Danielle L. Gray, Kayode D. Oshin, Tomislav Pintauer, Jennifer R. Connell, Margaret E. Mraz

Publikováno v: Acta Crystallographica Section E: Crystallographic Communications
Acta Crystallographica Section E: Crystallographic Communications, Vol 71, Iss 7, Pp 847-851 (2015)

In the crystal, weak Cu⋯Cl inter­actions between symmetry-related mol­ecules create a dimerization with a chloride occupying the apical position of the square-pyramidal geometry typical of many copper(II) chloride hetero-scorpionate complexes.