Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Toby J. Blundell"'
Publikováno v:
Magnetochemistry, Vol 9, Iss 3, p 64 (2023)
We report rf-penetration depth measurements of the quasi-2D organic superconductor β″-(BEDT-TTF)2[(H2O)(NH4)2Cr(C2O4)3]·18-crown-6, which has the largest separation between consecutive conduction layers of any 2D organic metal with a single packi
Externí odkaz:
https://doaj.org/article/8017a176e7884897b6884831ed71dc4f
Autor:
Helen R. Sharpe, Ana M. Geer, Laurence J. Taylor, Benjamin M. Gridley, Toby J. Blundell, Alexander J. Blake, E. Stephen Davies, William Lewis, Jonathan McMaster, David Robinson, Deborah L. Kays
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Metal-mediated activation of CO for C-C coupling reactions is a valuable approach to carbon monoxide valorization. Here, the authors use low-coordinate iron(II) complexes for the selective scission and homologation of CO affording unusual squaraines
Externí odkaz:
https://doaj.org/article/345eb1f0dbd64225b086da22de3b273c
Autor:
Andrew J. Valentine, Ana M. Geer, Toby J. Blundell, Will Tovey, Matthew J. Cliffe, E. Stephen Davies, Stephen P. Argent, William Lewis, Jonathan McMaster, Laurence J. Taylor, Daniel Reta, Deborah L. Kays
Publikováno v:
Dalton Transactions, 2022, Vol.51(47), pp.18118-18126 [Peer Reviewed Journal]
Two-coordinate transition metal complexes are exciting candidates for single-molecule magnets (SMMs) because their highly axial coordination environments lead to sizeable magnetic anisotropy. We report a series of five structurally related two-coordi
Publikováno v:
Dalton Transactions.
Molecular and longer-scale organisation of cations and anions in this silica organic framework (SOF) material built from a diamine and hexacoordinated silicon catecholate anion leads to porous crystals.
Autor:
Toby J. Blundell, Alexander L. Morritt, Elizabeth K. Rusbridge, Luke Quibell, Jakob Oakes, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Tomofumi Kadoya, Jun-ichi Yamada, Simon J. Coles, Jeppe Christensen, Lee Martin
We present the synthesis, crystal structures and conducting properties of six new BEDT-TTF radical-cation salts with the tris(oxalato)gallate or -iridate anion. The use of halobenzenes gives 4 : 1 β′′ metallic or superconducting salts with tris(
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a2040dcaa4a7455f2638c3aa3c025c70
https://eprints.soton.ac.uk/470079/
https://eprints.soton.ac.uk/470079/
Autor:
Hiroshi Nishimoto, Yasuhiro Nakazawa, Michael Brannan, Tomofumi Kadoya, Lee Martin, Hiroki Akutsu, Toby J. Blundell, Jun-ichi Yamada
Publikováno v:
Chemical Communications. 57:5406-5409
We report the first example of a chiral BDH-TTP radical-cation salt. Chirality is induced in the structure via the use of a chiral spiroboronate anion where three stereocentres are present, one on each chiral ligand and one on the boron centre. Despi
Autor:
Toby J, Blundell, Jordan R, Lopez, Kathryn, Sneade, John D, Wallis, Hiroki, Akutsu, Yasuhiro, Nakazawa, Simon J, Coles, Claire, Wilson, Lee, Martin
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(12)
We report the first examples of radical-cation salts of BEDT-TTF with spiroborate anions [B(mandelate)
Autor:
Toby J. Blundell, Jordan R. Lopez, Kathryn Sneade, John D. Wallis, Hiroki Akutsu, Yasuhiro Nakazawa, Simon J. Coles, Claire Wilson, Lee Martin
We report the first examples of radical-cation salts of BEDT-TTF with spiroborate anions [B(mandelate)2]− and [B(2-chloromandelate)2]−, synthesized from either enantiopure or racemic bidentate mandelate or chloromandelate ligands. In the salts pr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d7dea275c10898b1b05dd6212886a066
https://irep.ntu.ac.uk/id/eprint/46082/1/1524073_Martin.pdf
https://irep.ntu.ac.uk/id/eprint/46082/1/1524073_Martin.pdf
Autor:
Deborah L. Kays, Andrew James Valentine, William Lewis, Toby J. Blundell, Jonathan McMaster, Alexander J. Blake, Laurence J. Taylor
Publikováno v:
Chemical Communications. 56:8139-8142
The reaction between a two-coordinate Co(ii) diaryl complex and "GaI" affords 2,6-Pmp2C6H3CoGa3I5, in a new geometry for a heavier group 13-transition metal cluster. Experimental and computational investigations show that this compound is best descri
Autor:
Hiroki Akutsu, Jonathan I Short, Songjie Yang, Toby J. Blundell, Yasuhiro Nakazawa, Lee Martin, John D. Wallis, Sara J. Krivickas
Publikováno v:
Chemical Communications. 56:9497-9500
Materials exhibiting both chirality and conductivity do not exist in nature and very few examples have been synthesised. We report here the synthesis of a chiral molecular metal which remains metallic down to at least 4.2 K. This material also exhibi