Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Tobias Wütz"'
Germa- and Stanna-closo-dodecaborate in Reaction with [PdCl2(Xantphos)]: P–C and B–H Bond Activation
Publikováno v:
Organometallics. 31:7044-7051
The two nucleophilic heteroborates germa-closo-dodecaborate and stanna-closo-dodecaborate show different reactivity toward the electrophile [PdCl2(Xantphos)]: In the case of the germanium ligand we found straightforward substitution of one chloride l
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::56b0ad3e47ae01b8f960cf753cf4e8c8
https://doi.org/10.1021/om300438x
https://doi.org/10.1021/om300438x
Autor:
Claudia Nickl, Sebastian Fleischhauer, Tobias Wütz, Torben Gädt, Anita Frank, Lars Wesemann, Klaus Eichele, Jörg-Alexander Dimmer
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 44(10)
The oxidation of closo-heteroborates [GeB11H11](2-) and [SnB11H11](2-) is presented. Upon oxidation germa-closo-dodecaborate yields a symmetrical dimer exhibiting a Ge-Ge bond between two clusters. This dimer shows sulphur insertion into the Ge-Ge bo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::65b4620940a35854bf2f0741c3b9b0b1
https://pubmed.ncbi.nlm.nih.gov/25664571
https://pubmed.ncbi.nlm.nih.gov/25664571
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 42(3)
The heteroborate stanna-closo-dodecaborate shows double substitution in the reaction with alkylated acetonitrile. The reaction product, the charge compensated E,E-isomer, was isomerized into the Z,Z-isomer and hydrogenated at the double bonds. Furthe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11bae4c5d595678d82e79fda7034dba5
https://pubmed.ncbi.nlm.nih.gov/23111556
https://pubmed.ncbi.nlm.nih.gov/23111556