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Carbonyl sulfide (COS) is implicated in prebiotic chemistry, and recent work on COS/H2S donors has invigorated COS chemistry. We demonstrate that [TpM(CO)3]- (M=Mo,W) react with S8 to form COS, but form [TpW(CO)2]2Se3 not COSe upon reaction with Se.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ffb01da32f49c991fd4dda3bb8204ed0
https://doi.org/10.26434/chemrxiv-2023-hp0mt
https://doi.org/10.26434/chemrxiv-2023-hp0mt
