Unexpected molecular dynamics of ethanol in hydrogen-bonded binary mixtures, ethanol-octanol and ethanol-water

Autor: Ingo Hoffmann, Firoz Malayil Kalathil, Tobias Lopian, Didier Touraud, Orsolya Czakkel, Marie Plazanet, Christiane Alba-Simionesco

Publikováno v: EPJ Web of Conferences
EPJ Web of Conferences, 2022, QENS/WINS 2022 – 15th Edition of the QENS Series and 10th of the WINS Workshops San Sebastian (Online), Spain, May 23-27, 2022, 272, pp.01003. ⟨10.1051/epjconf/202227201003⟩
EPJ Web of Conferences, 2022, 272, pp.01003. ⟨10.1051/epjconf/202227201003⟩

International audience; In view of getting a quantitative picture of the dynamics in mixtures of hydrogen-bonded liquids, in particular the ternary water-ethanol-octanol, we examine in this paper the dynamics of two binary systems: ethanol-water and

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b250166d3222d1d6801c5cde23bd45a6
https://hal.science/hal-03876668

Combined molecular dynamics (MD) and small angle scattering (SAS) analysis of organization on a nanometer-scale in ternary solvent solutions containing a hydrotrope

Autor: Sebastian, Schöttl, Tobias, Lopian, Sylvain, Prévost, Didier, Touraud, Isabelle, Grillo, Olivier, Diat, Thomas, Zemb, Dominik, Horinek

Publikováno v: Journal of colloid and interface science. 540

Mixtures of three solvents, with two immiscible liquids and a third one miscible to both - the solvotrope, may exhibit structuration. We explore the phase diagram of n-octanol/ethanol/water, where ethanol is the hydrotrope, varying composition from t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::fac04a94d585dbf89065d64871f25c64
https://pubmed.ncbi.nlm.nih.gov/30690387

How to explain microemulsions formed by solvent mixtures without conventional surfactants

Autor: Tobias Lopian, Olivier Diat, Thomas Zemb, Dominik Horinek, Sylvain Prévost, Sebastian Schöettl, Julien Marcus, Didier Touraud, Stjepan Marčelja, Michael L. Klossek, Werner Kunz

Publikováno v: Proceedings of the National Academy of Sciences of the United States of America
Proceedings of the National Academy of Sciences of the United States of America, 2016, 113 (16), pp.4260-4265. ⟨10.1073/pnas.1515708113⟩
Proceedings of the National Academy of Sciences of the United States of America, National Academy of Sciences, 2016, 113 (16), pp.4260-4265. ⟨10.1073/pnas.1515708113⟩
'Proceedings of the National Academy of Sciences of the USA ', vol: 113, pages: 4260-4265 (2016)

International audience; Ternary solutions containing one hydrotrope (such as ethanol) and two immiscible fluids, both being soluble in the hydrotrope at any proportion, show unexpected solubilization power and allow strange but yet unexplained membra

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0eb8b5b22f52995ab6254765695c6646
https://hal.umontpellier.fr/hal-02116966

Morphologies Observed in Ultraflexible Microemulsions with and without the Presence of a Strong Acid

Autor: Thomas Zemb, Dominik Horinek, Sebastian Schöttl, Sylvain Prévost, Tobias Lopian, Stéphane Pellet-Rostaing, Werner Kunz

Publikováno v: ACS Central Science
ACS Central Science, ACS Publications, 2016, 2 (7), pp.467-475. ⟨10.1021/acscentsci.6b00116⟩
ACS Central Science, Vol 2, Iss 7, Pp 467-475 (2016)
ACS Central Science, 2016, 2 (7), pp.467-475. ⟨10.1021/acscentsci.6b00116⟩
'ACS Central Science ', vol: 2, pages: 467-475 (2016)

We show that three different morphologies exist near the two-phase boundary of ternary systems containing a hydrotropic cosolvent. Based on synchrotron small- and wide-angle X-ray scattering combined with molecular dynamics, we rationalize the specif

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4ea573c3634b2b7a99279d0a05137d5a
https://hal.archives-ouvertes.fr/hal-01572895/document