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Publikováno v:
Applied Catalysis A: General. 156:267-283
Isobutane/2-butene alkylation was carried out in a semibatch slurry reactor using the hydrogen and lanthanum exchanged form of hexagonal faujasite (EMT, Si Al bulk ratio of 3.5) as catalysts. 51% La exchange in the EMT sample (La-EMT-51) gave a very
Publikováno v:
Applied Catalysis A: General. 144:305-317
The alkylation of isobutane with 2-butene has been studied in a slurry reactor on the iso-structural H-SAPO-37 and dealuminated faujasite (FAU) catalysts. It was found that mainly dimerization takes place on H-SAPO-37 by producing C 8 olefins. In the
Publikováno v:
Applied Catalysis A: General. 137:235-253
The isobutane/2-butene alkylation has been catalysed by acidic cubic faujasites (H-FAU and CeY-98) and a hexagonal faujasite (H-EMT) in a semibatch slurry reactor. H-EMT exhibited the best results during the reaction with respect to an improved deact
Publikováno v:
Catalysis Letters. 33:127-134
A solid superacidic Nafion-H polymer was examined as a catalyst for isobutane/2-butene alkylation and compared with a cerium-exchanged Y zeolite. Both catalysts demonstrate initial alkylation activity with rapid decrease in alkylation selectivity. Th
Publikováno v:
Catalysis Letters. 28:203-209
The alkylation of isobutane with 2-butene on hexagonal (protonated form = H EMT, investigated, for the first time on this reaction) and cubic faujasite (protonated form = H FAU) with Si/Al ratios of 3.5 was studied at 80°C and compared with the resu