Zobrazeno 1 - 10
of 204
pro vyhledávání: '"Timothy P, Hanusa"'
Publikováno v:
ACS Organic & Inorganic Au, Vol 4, Iss 6, Pp 658-672 (2024)
Externí odkaz:
https://doaj.org/article/a0de72e11ad6430e9758e41ab5cdc8dd
Autor:
Ross F. Koby, Nicholas R. Rightmire, Nathan D. Schley, Timothy P. Hanusa, William W. Brennessel
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 1856-1863 (2019)
As a synthesis technique, halide metathesis (n RM + M'Xn → RnM' + n MX) normally relies for its effectiveness on the favorable formation of a metal halide byproduct (MX), often aided by solubility equilibria in solution. Owing to the lack of signif
Externí odkaz:
https://doaj.org/article/d75867991305493db50a886d41fb39d6
Publikováno v:
ACS Omega, Vol 3, Iss 7, Pp 8149-8159 (2018)
Externí odkaz:
https://doaj.org/article/cf52ca7d8a8d4a5f81b44da4de98de88
Autor:
Lauren E. Wenger, Nicholas M. Shawver, William W. Brennessel, Brian K. Long, Timothy P. Hanusa
Publikováno v:
Organometallics. 41:3718-3723
Autor:
Isaiah R. Speight, Timothy P. Hanusa
Publikováno v:
Molecules, Vol 25, Iss 3, p 570 (2020)
Owing to the strength of the C−F bond, the ‘direct’ preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds.
Externí odkaz:
https://doaj.org/article/dc7aeb5599924a868ab06cb356ab45b9
Autor:
Henry P. DeGroot, Timothy P. Hanusa
Publikováno v:
Organometallics. 40:3516-3525
Publikováno v:
Angewandte Chemie. 133:21344-21348
Autor:
Ross F. Koby, Nicholas R. Rightmire, Nathan D. Schley, Timothy P. Hanusa, William W. Brennessel, Brian K. Long, Alicia M. Doerr
Publikováno v:
Chemistry – A European Journal. 27:8195-8202
Without solvents present, the often far-from-equilibrium environment in a mechanochemically driven synthesis can generate high-energy, non-stoichiometric products not observed from the same ratio of reagents used in solution. Ball milling 2 equiv. K[
Autor:
Henry P. DeGroot, Timothy P. Hanusa
Publikováno v:
Encyclopedia of Inorganic and Bioinorganic Chemistry. :1-13
Autor:
Timothy P. Hanusa, Ross F. Koby, Nicholas R. Rightmire, Brian K. Long, Alicia M. Doerr, Nathan D. Schley
Publikováno v:
Angewandte Chemie International Edition. 59:9542-9548
Milling two equivalents of K[1,3-(SiMe3 )2 C3 H3 ] (=K[A']) with MgX2 (X=Cl, Br) produces the allyl complex [K2 MgA'4 ] (1). Crystals grown from toluene are of the solvated species [((η6 -tol)K)2 MgA'4 ] ([1⋅2(tol)]), a trimetallic monomer with bo