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pro vyhledávání: '"Timothy M. Alligrant"'
Autor:
Keith J. Stevenson, Richard M. Crooks, Timothy M. Alligrant, Morgan J. Anderson, Radhika Dasari
Publikováno v:
Langmuir. 30:13462-13469
We report on the effect of convection on electrochemically active collisions between individual Pt nanoparticles (PtNPs) and Hg and Au electrodes. Compared to standard electrochemical cells utilizing Hg and Au ultramicroelectrodes (UMEs) used in prev
Publikováno v:
The Journal of Physical Chemistry C. 116:20447-20457
Mono- and dibasic phthalate bases (HP– and P2–) interact with 1,4-hydroquinone (1,4-H2Q) in acetonitrile through hydrogen bonding to form molecular complexes that oxidize at easier (less positive) potentials than pure 1,4-H2Q. The relatively larg
Autor:
Timothy M. Alligrant, Julio C. Alvarez
Publikováno v:
The Journal of Physical Chemistry C. 115:10797-10805
An example of proton-coupled electron transfer (PCET) comprised by the electrochemical oxidation of 1,4-hydroquinone (1,4-H2Q) in acetonitrile was studied in the presence of Bronsted bases in acetonitrile. Of the two types of bases studied, the negat
Publikováno v:
Electrochimica Acta. 55:6507-6516
This report seeks to address the role of hydrogen bonding with Bronsted acids and bases in proton-coupled electron transfer (PCET) as it pertains to concerted or stepwise pathways of quinone (Q) and hydroquinone (QH2) electrochemistry. This study was
Publikováno v:
Langmuir : the ACS journal of surfaces and colloids. 31(2)
We report electrochemical catalytic amplification of individual collisions between ∼57 nm diameter Pt nanoparticles (Pt NPs) and 12.5 μm diameter Au ultramicroelectrodes modified with passivating, electrostatically assembled polyelectrolyte multil
Autor:
Timothy M. Alligrant, Julio Alvarez
Publikováno v:
ECS Meeting Abstracts. :1476-1476
not Available.