Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Timo Trageser"'
Publikováno v:
IUCrData, Vol 4, Iss 7, p x190959 (2019)
The molecular structure of the title compound, C18H15ISi, which crystallizes in the space group C2/c, does not exhibit any unusual features. Two weak C—H...π interactions may help to consolidate the packing. The present structure is not isostructu
Externí odkaz:
https://doaj.org/article/557700a61ffe4058b662005a09534961
Autor:
Jannik Gilmer, Timo Trageser, Luis Čaić, Alexander Virovets, Michael Bolte, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Science. 14:4589-4596
9-Borafluorene-based diboranes and silylboranes spontaneously add to CC or CC bonds. Despite their different charge and bond polarization, key orbital interactions of substrate activation are identical for both valence isoelectronic derivatives
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ed50d81a1f76313e0874a1ac995f422f
https://doi.org/10.1039/d3sc01395b
https://doi.org/10.1039/d3sc01395b
Publikováno v:
Angewandte Chemie International Edition. 60:13500-13506
The intriguing (μ-hydrido)diboranes(4) with their prominent pristine representative [B2 H5 ]- have mainly been studied theoretically. We now describe the behavior of the planarized tetraaryl (μ-hydrido)diborane(4) anion [1H]- in cycloaddition react
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d433bd408b50dc7fc3a9198a14019a5
https://doi.org/10.1002/anie.202103427
https://doi.org/10.1002/anie.202103427
Publikováno v:
European Journal of Inorganic Chemistry. 2020:4148-4162
Subvalent boron compounds contain boron atoms with oxidation numbers lower than +III. Over the last decades, the development of isolable derivatives has relied heavily on the use of specially designed ligands capable of stabilizing the electron‐ric
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59b7d44ad53d6922860e72155ef5bbc9
https://doi.org/10.1002/ejic.202000786
https://doi.org/10.1002/ejic.202000786
Publikováno v:
Angewandte Chemie (International Ed. in English)
The intriguing (μ‐hydrido)diboranes(4) with their prominent pristine representative [B2H5]− have mainly been studied theoretically. We now describe the behavior of the planarized tetraaryl (μ‐hydrido)diborane(4) anion [1H]− in cycloaddition
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::11bc7412d18589d3ed61d92eff097a43
https://pubmed.ncbi.nlm.nih.gov/33740318
https://pubmed.ncbi.nlm.nih.gov/33740318
Publikováno v:
Angewandte Chemie (International Ed. in English)
The tetraaryl μ‐hydridodiborane(4) anion [2H]− possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9‐H‐9‐borafluorene (HBFlu) furnishes the B3 cluster K[3], with a triangular boron core linked through tw
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b597405edfef82c9e2b61c06173a5b96
https://pubmed.ncbi.nlm.nih.gov/32058652
https://pubmed.ncbi.nlm.nih.gov/32058652
Front Cover: Anionic Organoboranes: Delicate Flowers Worth Caring for (Eur. J. Inorg. Chem. 44/2020)
Publikováno v:
European Journal of Inorganic Chemistry. 2020:4146-4146
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ad60f766fc883b5ff41a3a97ca2d482e
https://doi.org/10.1002/ejic.202000989
https://doi.org/10.1002/ejic.202000989
Autor:
Thomas, Kaese, Timo, Trageser, Hendrik, Budy, Michael, Bolte, Hans-Wolfram, Lerner, Matthias, Wagner
Publikováno v:
Chemical Science
Targeted C(sp3)–H activation or nucleophilic substitution reactions have been achieved through the interaction of a diborane dianion with haloalkanes.
Organoboranes are among the most versatile and widely used reagents in synthetic chemistry.
Organoboranes are among the most versatile and widely used reagents in synthetic chemistry.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::ca46e00a35a2e6a5edc9561b0204a1c3
https://pubmed.ncbi.nlm.nih.gov/29780520
https://pubmed.ncbi.nlm.nih.gov/29780520
Publikováno v:
Chemical communications (Cambridge, England). 51(87)
The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility to the air- and water-stable green luminophore.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b24953516cc09eacf6c332baf15a51a4
https://pubmed.ncbi.nlm.nih.gov/26366478
https://pubmed.ncbi.nlm.nih.gov/26366478