Zobrazeno 1 - 10
of 28
pro vyhledávání: '"Timo Trageser"'
Autor:
Jannik Gilmer, Timo Trageser, Luis Čaić, Alexander Virovets, Michael Bolte, Hans-Wolfram Lerner, Felipe Fantuzzi, Matthias Wagner
Publikováno v:
Chemical Science. 14:4589-4596
9-Borafluorene-based diboranes and silylboranes spontaneously add to CC or CC bonds. Despite their different charge and bond polarization, key orbital interactions of substrate activation are identical for both valence isoelectronic derivatives
Publikováno v:
IUCrData, Vol 4, Iss 7, p x190959 (2019)
The molecular structure of the title compound, C18H15ISi, which crystallizes in the space group C2/c, does not exhibit any unusual features. Two weak C—H...π interactions may help to consolidate the packing. The present structure is not isostructu
Externí odkaz:
https://doaj.org/article/557700a61ffe4058b662005a09534961
Publikováno v:
Angewandte Chemie International Edition. 60:13500-13506
The intriguing (μ-hydrido)diboranes(4) with their prominent pristine representative [B2 H5 ]- have mainly been studied theoretically. We now describe the behavior of the planarized tetraaryl (μ-hydrido)diborane(4) anion [1H]- in cycloaddition react
Publikováno v:
European Journal of Inorganic Chemistry. 2020:4148-4162
Subvalent boron compounds contain boron atoms with oxidation numbers lower than +III. Over the last decades, the development of isolable derivatives has relied heavily on the use of specially designed ligands capable of stabilizing the electron‐ric
Publikováno v:
Angewandte Chemie (International Ed. in English)
The intriguing (μ‐hydrido)diboranes(4) with their prominent pristine representative [B2H5]− have mainly been studied theoretically. We now describe the behavior of the planarized tetraaryl (μ‐hydrido)diborane(4) anion [1H]− in cycloaddition
Publikováno v:
Angewandte Chemie (International Ed. in English)
The tetraaryl μ‐hydridodiborane(4) anion [2H]− possesses nucleophilic B−B and B−H bonds. Treatment of K[2H] with the electrophilic 9‐H‐9‐borafluorene (HBFlu) furnishes the B3 cluster K[3], with a triangular boron core linked through tw
Front Cover: Anionic Organoboranes: Delicate Flowers Worth Caring for (Eur. J. Inorg. Chem. 44/2020)
Publikováno v:
European Journal of Inorganic Chemistry. 2020:4146-4146
Autor:
Thomas, Kaese, Timo, Trageser, Hendrik, Budy, Michael, Bolte, Hans-Wolfram, Lerner, Matthias, Wagner
Publikováno v:
Chemical Science
Targeted C(sp3)–H activation or nucleophilic substitution reactions have been achieved through the interaction of a diborane dianion with haloalkanes.
Organoboranes are among the most versatile and widely used reagents in synthetic chemistry.
Organoboranes are among the most versatile and widely used reagents in synthetic chemistry.
Publikováno v:
Chemical communications (Cambridge, England). 51(87)
The high-yield synthesis of a boron-doped [4]helicene was achieved through a Ni-mediated Yamamoto C-C-coupling reaction; the moderate distortion of the molecular scaffold confers excellent solubility to the air- and water-stable green luminophore.
Autor:
Trageser, Timo1 (AUTHOR), Bebej, Dariusz1 (AUTHOR), Bolte, Michael1 (AUTHOR), Lerner, Hans‐Wolfram1 (AUTHOR), Wagner, Matthias1 (AUTHOR) Matthias.Wagner@chemie.uni-frankfurt.de
Publikováno v:
Angewandte Chemie. 6/7/2021, Vol. 133 Issue 24, p13612-13618. 7p.