Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Tim Oswald"'
Publikováno v:
Inorganics, Vol 11, Iss 10, p 377 (2023)
A new synthetic pathway to various mono-alkyl-substituted phosphinoboranes HRP–BH2–NMe3 has been developed. The new synthetic route starting from alkyl halides and NaPH2 followed by metalation and salt metathesis is performed in a one-pot procedu
Externí odkaz:
https://doaj.org/article/ca101e60ca84479db2f58325912121f6
Publikováno v:
Acta Crystallographica Section E: Crystallographic Communications, Vol 73, Iss 5, Pp 691-693 (2017)
The isotypic crystal structures of two titanocene complexes containing an EMe3 unit (E = Al, Ga; Me = methyl) with two μ2-coordinating methyl groups, namely [μ-1(η5)-(adamantan-1-yl-2κC1)cycylopentadienyl]di-μ2-methyl-methyl-2κC-[1(η5)-pentame
Externí odkaz:
https://doaj.org/article/b4e42fb8512e4725bbcf4aa164cd81a3
Publikováno v:
Organometallics. 38:829-843
The reaction of penta- and benzofulvene complexes of group 4 (M = Ti, Zr) with different phosphorus ylides is reported. Employing the bis(η5:η1-pentafulvene)titanium complexes Ti1a and Ti1b, the reactions with the corresponding phosphorus ylides Y1
Publikováno v:
Acta Crystallographica Section C Structural Chemistry. 74:442-451
Metallocene dihalides and derivatives thereof are of great interest as precursors for catalysts in polymerization reactions, as antitumor agents and, due to their increased stability, as suitable starting materials in salt metathesis reactions and th
Publikováno v:
Organometallics. 37:415-421
The reaction of Cp*MCl3 (M = Zr, Zr1; M = Hf, Hf1) with the reducing agent Na/Hg (20% Na) and with sterically encumbered pentafulvenes adamantylidenepentafulvene AdFv, 6,6′-di-p-tolylpentafulvene pTol2Fv, and benzofulvenes adamantylidenebenzofulven
Autor:
Marc Schmidtmann, Tina Gelert, Rüdiger Beckhaus, Tim Oswald, Christian Lasar, Thorsten Klüner
Publikováno v:
Angewandte Chemie International Edition. 56:12297-12301
The reaction of bis(η5 :η1 -pentafulvene)titanium complexes with an allylidenephosphorylide Ph3 P=C(H)- C(H)=CH2 leads to binuclear zigzag hexapentaene titanium complexes (Ti2a, Ti2b). The formation of the central C6 H4 unit can be described as a s
Publikováno v:
Acta crystallographica. Section C, Structural chemistry. 74(Pt 4)
Metallocene dihalides and derivatives thereof are of great interest as precursors for catalysts in polymerization reactions, as antitumor agents and, due to their increased stability, as suitable starting materials in salt metathesis reactions and th
Publikováno v:
Journal of Pediatric Orthopaedics B. 24:40-45
This case study discusses a 13-year-old girl diagnosed with a displaced Salter Harris II fracture of the proximal femoral epiphysis post reduction of a dislocated hip. Radiographs before reduction revealed a small fracture of the inferomedial femoral
Publikováno v:
Zeitschrift für Kristallographie-New Crystal Structures, Vol 231, Iss 2, Pp 637-639 (2016)
C14H23Cl2OTi, monoclinic, P21/c (no. 14), a = 12.3163(7) Å, b = 9.0436(5) Å, c = 15.0774(8) Å, β = 103.245(2)°, V = 1634.70(16) Å3, Z = 4, R gt (F) = 0.0418, wR ref (F 2) = 0.1142, T = 200(2) K.
Autor:
Tim, Oswald, Tina, Gelert, Christian, Lasar, Marc, Schmidtmann, Thorsten, Klüner, Rüdiger, Beckhaus
Publikováno v:
Angewandte Chemie (International ed. in English). 56(40)
The reaction of bis(η