Zobrazeno 1 - 10
of 24
pro vyhledávání: '"Tim F. Rozan"'
Publikováno v:
Environmental Science & Technology. 37:3845-3852
Pseudovoltammetry was used to evaluate the actual Pb complexation occurring in natural water samples of varying oxygen and sulfide concentration. In pseudovoltammetry, the potential at which metal-ligand complexes are broken up to form the metal amal
Publikováno v:
Estuaries. 25:1088-1096
Solid and colloidal iron oxides are commonly involved in early diagenesis. More readily available soluble Fe(III) should accelerate the cycling of iron (Fe) and sulfur (S) in sediments. Experiments with synthetic solutions (Taillefert et al. 2000) sh
Autor:
Shufen Ma, Tim F. Rozan, Brian T. Glazer, Robert E. Trouwborst, Martial Taillefert, Lexia M. Valdes, Julian Herszage, George W. Luther, Kent S. Price
Publikováno v:
Limnology and Oceanography. 47:1346-1354
We conducted a study to determine the seasonal relationship between iron, sulfur, and phosphorus in the upper sediments and pore waters of a shallow intercoastal bay. From April 1999 to September 2000, sediment cores were collected from Rehoboth Bay,
Autor:
George W. Luther, Tim F. Rozan
Publikováno v:
Marine Chemistry. 77:1-6
An anion chromatography with ultraviolet detection (IC/UV) method was developed to simultaneously measure NO 3 − , NO 2 − , and HS − concentrations in saline (pore)waters. This method achieves nanomolar detection limits without the need for a C
Autor:
Donald B. Nuzzio, Martial Taillefert, Carol A. Di Meo, Richard A. Lutz, Tim F. Rozan, George W. Luther, S. Craig Cary, Timothy M. Shank
Publikováno v:
Nature. 410:813-816
The physiology and biochemistry of many taxa inhabiting deep-sea hydrothermal vents have been elucidated; however, the physicochemical factors controlling the distribution of these organisms at a given vent site remain an enigma after 20 years of res
Autor:
Gaboury Benoit, Tim F. Rozan
Publikováno v:
Journal of Paleolimnology. 25:455-465
210Pb has been used for more than two decades to provide the geochronology of annually deposited sediments and to construct pollution histories. Evidence from some lakes suggests that this radionuclide may be adequately mobile to compromise dating re
Publikováno v:
Analytica Chimica Acta. 415:175-184
Free polysulfides (S42−), elemental sulfur (S0) and bisulfide (HS−) can be separated at discrete peak potentials using either cyclic voltammetry (CV) or linear sweep voltammetry (LS) with extremely fast scan rates. A scan rate of 1000 mV/s was fo
Autor:
Tim F. Rozan, Gaboury Benoit
Publikováno v:
Geochimica et Cosmochimica Acta. 63:3311-3319
Copper speciation was determined monthly at seven sites on four rivers in southern New England to understand which geochemical factors control free metal ion concentrations in river water. Samples were conventionally filtered (
Publikováno v:
Environmental Science & Technology. 33:1766-1770
Complexation by dissolved humic substances has an important influence on trace metal behavior in natural systems. Unfortunately, few analytical techniques are available with adequate sensitivity and selectivity to measure free metal ions reliably at
Autor:
Tim F. Rozan, Gaboury Benoit
Publikováno v:
Geochimica et Cosmochimica Acta. 63:113-127
The particle concentration effect (p.c.e.) is an unexpected decline in partition coefficients (Kd) as suspended particulate matter (SPM) increases. This anomaly has been attributed to a variety of causes, but most often to the existence of colloidal