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Biomimetic oxidation of plant protecting agents

Autor: Gerhard Görlitz, Till Einig, Bernd Neidhart

Publikováno v: Fresenius Journal of Analytical Chemistry. 355:71-77

The suitability of two in vitro oxidation systems as chemical models for the biological degradation of plant protecting agents has been investigated. As representative herbicides diclofop, fenoxaprop, isoproturon, linuron and monolinuron have been ox

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::61a83bceebd52f37db4dce5a79eaf24e
https://doi.org/10.1007/s0021663550071

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Ligand- and oxidation state-dependence of structure of triazenido-bridged complexes with face-to-face and open-book dirhodium cores: MO studies and the crystal structure of [Rh2(µ-CO)(bipy)(dppm)(µ-RNNNR)2][PF6]2·2CH2Cl2(R =p-tolyl)

Autor: Neil G. Connelly, Carlo Mealli, A. Guy Orpen, Gabriel Garcia Herbosa, Till Einig, Philippa M. Hopkins, Georgina M. Rosair

Publikováno v: J. Chem. Soc., Chem. Commun.. :143-145

Treatment of [{Rh2l(CO)(bipy)(µ-RNNNR)2}2][PF6]22 with AgPF6 and dppm gives [Rh2(µ-CO)(bipy)(L–L)(µ-RNNNR)2]2+(5; L–L = dppm), X-ray and MO studies on which show that it may be viewed as an open-book [Rh2]6+ core bridged by a ‘ketonic’ CO2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ccedcef8c7f363474f868a2ca83e292f
https://doi.org/10.1039/c39920000143

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