Zobrazeno 1 - 10
of 19
pro vyhledávání: '"Thorsten Morawitz"'
Publikováno v:
Acta Crystallographica Section E, Vol 64, Iss 3, Pp m496-m496 (2008)
The title compound, [Re2(OH)(C10H8N2)2(CO)6][ReO4], is a mixed-valence rhenium compound containing discrete anions and cations. The ReI atoms are in a slightly distorted octahedral environment, whereas the ReVII atoms show the typical tetrahedral coo
Externí odkaz:
https://doaj.org/article/72cfad36a1544f4c96cc86af2d2c2a89
Publikováno v:
Journal of Organometallic Chemistry. 693:3878-3884
Two dinuclear RhI-cyclooctadiene complexes [1,4-(cod)Rh(B(R’)pz2)-C6H4-(B(R’)pz2)Rh(cod)], linked by a ditopic scorpionate ligand, have been prepared and fully characterized (R′ = Ph (2), C6F5 (2F); pz = pyrazolide). Both compounds were tested
Autor:
Fan Zhang, Michael Bolte, Matthias Wagner, Thorsten Morawitz, Hans-Wolfram Lerner, Jan W. Bats
Publikováno v:
Organometallics. 27:5067-5074
Treatment of the ditopic phenylene-bridged bis(pyrazol-1-yl)borate K2[m-C6H4(B(tBu)pz2)2] (m-1) with [Mn(CO)5Br] results in ligand degradation with formation of the pyrazabole-bridged macrocyclic d...
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 634:1570-1574
The synthesis and full characterization of the sterically demanding ditopic lithium bis(pyrazol-1-yl)borates Li2[p-C6H4(B(Ph)pzR2)2] is reported (pzR = 3-phenylpyrazol-1-yl (3Ph), 3-t-butylpyrazol-1-yl (3tBu)). Compound 3Ph crystallizes from THF as T
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 634:1409-1414
The synthesis and characterization of the ditopic bis(pyrazol-1-yl)borate ligand Li2[p-C6H4(B(C6F5)pz2)2] is reported (pz = pyrazol-1-yl). Compared to the corresponding t-butyl derivative Li2[p-C6H4(B(t-Bu)pz2)2], the C6F5-substituted scorpionate is
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 62:m1474-m1476
The crystal structure of the title compound, [Cu3(C9H7N2)3], consists of discrete CuI–phenylpyrazolyl trimers, with Cu atoms bridged by exo-bidentate phenylpyrazolyl ligands having short intramolecular Cu...Cu contacts [3.2076 (14)–3.2402 (14) Å
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 61:m2201-m2203
The title compound, [Cu2(C2H3O2)2(C26H24P2)3]·2C4H10O, crystallizes with one dicopper(I) unit located on a centre of inversion and two diethyl ether molecules in general positions. The Cu atoms exhibit slightly distorted tetrahedral coordination
Publikováno v:
Acta Crystallographica Section E: Structure Reports
The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa-hedral environment, whereas the Re(VII) atoms show the typi
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m294-m295
In the title compound, [Li(C4H8O)4][Cu3I4(C18H15P)2]·C4H8O, the three Cu atoms are μ2-bridged by three I atoms and a fourth I atom is bonded to the three Cu atoms in a μ3-bridging mode.
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 61:o4367-o4368
The title compound, C9H25N32+·2PF6−, consists of discrete hexafluorophosphate anions and 1,1,4,7,7-pentamethyldiethylenetriamine cations. The geometric parameters are in the usual ranges. Only one PF6− cation forms hydrogen bonds with bo