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Autor:
Thor L. Smith
Publikováno v:
Journal of Polymer Science: Polymer Symposia. 46:97-114
The equilibrium shear modulus G of network polymers increases rapidly with the chain concentration ν when ν ≳ 10−3 mol/cm3. This behavior is accounted for by the equation G=ΦnνRTΓ(1/λm) where Φn(=rt2/r00) may depend on n, the mean number o
Autor:
Thor L. Smith
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 35:39-50
Several equations containing two empirical constants are considered for representing G(t), G′(ω), J′(ω), and J(t) in the glass-to-rubber dispersion zone. With these equations, data on the NBS polyisobutylene can be closely represented. The rela
Autor:
Thor L. Smith
Publikováno v:
Journal of Polymer Science Part C: Polymer Symposia. 32:269-282
Macroscopic fracture is preceded by localized deformation and rupture processes that depend on the state of combined stress (i.e., on the stress state) and other test conditions as well as on polymer structure and morphology. To illustrate the effect
Autor:
Thor L. Smith, B. Haidar
Publikováno v:
Polymer. 32:2594-2600
The yield force (or stress) of polycarbonate in simple extension was studied to determine its dependence on deformation history, including the stretching rate, and temperature. At different temperatures, the stretching of a specimen at a constant rat
Autor:
Thor L. Smith, Churl S. Kim
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 28:2119-2126
A novel method has been developed and tested to determine accurately the linear coefficient of thermal expansion α of flexible films without subjecting a specimen to a tensile load continuously during the measurement of expansion data. Other methods
Autor:
B. Haidar, Thor L. Smith
Publikováno v:
Polymer. 31:1904-1908
Well annealed specimens of polycarbonate film were first subjected rapidly to a static elongation of 2.6% at 13 temperatures from −110 to 110°C. During stress relaxation at each temperature, the static strain was modulated with a sinusoidal tensil
Publikováno v:
Rubber Chemistry and Technology. 63:256-264
For three series of bimodal networks, the stress-relaxation rates and the tearing energies were shown to exhibit maxima at about the same concentrations of short chains as those at which the tensile strengths, reported earlier, also exhibit maxima. T
Autor:
Thor L. Smith, T. Ricco
Publikováno v:
Journal of Polymer Science Part B: Polymer Physics. 28:513-520
A study was made of the physical aging of an annealed polycarbonate film at a constant extension of 2.6% at 5 temperatures from 30 to 110°C. During stress relaxation at the constant extension, the storage modulus in tension, E′, was determined by
Autor:
Bassel Haidar, Thor L. Smith
Publikováno v:
Macromolecules. 23:3710-3712