Výsledky vyhledávání - "Thomas P, Spaniol"

Manipulating electron transfer – the influence of substituents on novel copper guanidine quinolinyl complexes

Autor: Joshua Heck, Fabian Metz, Sören Buchenau, Melissa Teubner, Benjamin Grimm-Lebsanft, Thomas P. Spaniol, Alexander Hoffmann, Michael A. Rübhausen, Sonja Herres-Pawlis

Publikováno v: Chemical science 13(28), 8274-8288 (2022). doi:10.1039/D2SC02910C

Chemical science 13(28), 8274 - 8288 (2022). doi:10.1039/D2SC02910C
Copper guanidine quinolinyl complexes act as good entatic state models due to their distorted structures leading to a high similarity between Cu(I) and Cu(II) complexes. For a b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::701b83b4ad345bb1329250b26cf88ab8
https://doi.org/10.1039/d2sc02910c

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Formate complexes of tri- and tetravalent titanium supported by a tris(phenolato)amine ligand

Autor: Akira Okumura, Priyabrata Ghana, Fabian Fink, Regina Schmidt, Alexander Hoffmann, Thomas P. Spaniol, Sonja Herres-Pawlis, Jun Okuda

Publikováno v: Dalton Transactions. 51:14345-14351

Titanium(iii) and titanium(iv) formate complexes supported by the sterically encumbering tris(phenolato)amine ligand (H3(O3N) = tris(4,6-di-tert-butyl-2-hydroxybenzyl)amine) are described.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f917b377f58cac3f8ad3b48721e7930e
https://doi.org/10.1039/d2dt01739c

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A Cationic Barium Hydride Complex Supported by an NNNN‐Type Macrocycle

Autor: Thomas Höllerhage, Thomas P. Spaniol, Ulli Englert, Jun Okuda

Publikováno v: Zeitschrift für anorganische und allgemeine Chemie : ZAAC = Journal of inorganic and general chemistry 649(4), e202200315 (2022). doi:10.1002/zaac.202200315

Zeitschrift für anorganische und allgemeine Chemie : ZAAC = Journal of inorganic and general chemistry e202200315 (2022). doi:10.1002/zaac.202200315
Published by Wiley-VCH, Weinheim

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08798fca6803b9d9052a29912196611c

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Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis

Autor: Thomas Höllerhage, Thomas P. Spaniol, Ambre Carpentier, Laurent Maron, Jun Okuda

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2022, 61 (7), pp.3309-3316. ⟨10.1021/acs.inorgchem.1c03894⟩

International audience; The use of the 15-membered NNNNN macrocyclic ligand Me(5)PACP (Me(5)PACP = 1,4,7,10,13-pentamethyl-1,4,7,10,13-pentaazacyclopentadecane) allowed the isolation of two cationic strontium hydride complexes by hydrogenolysis of be

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f18d107d00deab7ff574be011184604
https://hal.science/hal-03714655

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Deaggregation of Zinc Dihydride by Lewis Acids Including Carbon Dioxide in the Presence of Nitrogen Donors

Autor: Thomas P. Spaniol, Jun Okuda, Karl N. McCabe, Laurent Maron, Louis J. Morris, Florian Ritter

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2021, 60 (20), pp.15583-15592. ⟨10.1021/acs.inorgchem.1c02207⟩

International audience; Thermally sensitive polymeric zinc dihydride [ZnH2] (n) can conveniently be prepared by the reaction of ZnEt2 with [AlH3(NEt3)]. When reacted with CO2 (1 bar) in the presence of chelating N-donor ligands L-n = N,N,N',N'tetrame

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a98e26cf704db6286603ec3bcfbd163
https://pubmed.ncbi.nlm.nih.gov/34591456

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