Zobrazeno 1 - 10
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pro vyhledávání: '"Thomas M. de Swiet"'
Autor:
Thomas M. de Swiet
Publikováno v:
Journal of Magnetic Resonance. 174:331-334
For many applications, reducing sample resistance, rather than increasing probe Q or filling factor, is the only way to further improve the signal-to-noise ratio of cryogenically cooled NMR probes. In this paper, bounds are calculated for the minimum
Publikováno v:
The Journal of Physical Chemistry B. 106:8676-8680
Carbon-13 MAS refocused INADEQUATE experiments have been carried out on the polymer phase of CsC 6 0 and provide a complete and unambiguous assignment of the high-resolution carbon-13 MAS spectrum. This allows experimental Knight shifts for each carb
Autor:
Thomas M. de Swiet
Publikováno v:
The Journal of Chemical Physics. 112:8567-8572
Three-dimensional measurements of the 13C nuclear magnetic resonance (NMR) chemical shift in methyl-α-D-glucopyranoside are presented. One dimension measures the isotropic shift under ordinary magic angle spinning. In the remaining two dimensions, t
Autor:
Thomas M. de Swiet
Publikováno v:
The Journal of Chemical Physics. 110:5231-5237
A direct transform of the NMR chemical shift anisotropy, operating on data acquired under magic angle spinning conditions, yielding rotationally invariant quantities, is potentially a source of increased resolution in solid state NMR. The mathematica
Publikováno v:
The Journal of Chemical Physics. 108:6233-6239
Molecular diffusion during the application of magnetic field gradients can distort magnetic resonance images. A systematic characterization of these distortions in one dimension was performed using highly spin-polarized xenon gas. By varying the stre
Publikováno v:
Chemical Physics Letters. 285:59-63
The NMR chemical shielding in a solid powder sample produces featured, but broad, lineshapes, or powder patterns, because the shielding experienced by a nuclear spin depends on the spatial orientation of its local molecular frame with respect to the
Autor:
Thomas M. de Swiet, Pabitra N. Sen
Publikováno v:
The Journal of Chemical Physics. 104:206-209
We present a closed form expression for the diffusion coefficient in a dilute suspension of reflecting spheres, which is valid for all times. Our result is in agreement with general long and short time asymptotic results, which have been used in the
Publikováno v:
Journal of Non-Crystalline Solids. 182:198-205
Two manifestations of diffractive behavior in diffusion in a porous medium are reviewed. The measured amplitude, M(q, t), in a pulsed field gradient spin echo (PGSE) experiment probes the pore structure using two length scales, the gradient length q
Autor:
Pabitra N. Sen, Thomas M. de Swiet
Publikováno v:
The Journal of Chemical Physics. 100:5597-5604
Transverse magnetization of spins diffusing in a bounded region in the presence of a constant field gradient is studied. We investigate the breakdown at short times of the much used formula for the Hahn echo amplitude in a constant gradient in unboun
Publikováno v:
Journal of Magnetic Resonance. 133:385-387
Limitations of resolution and absorption in standard chemical spectroscopic techniques have made it difficult to study fluids in sedimentary rocks. In this paper, we show that a chemical characterization of pore fluids may be obtained in situ by magi