In-situ spectroscopic probe of the intrinsic structure feature of single-atom center in electrochemical CO/CO2 reduction to methanol

Autor: Xinyi Ren, Jian Zhao, Xuning Li, Junming Shao, Binbin Pan, Aude Salamé, Etienne Boutin, Thomas Groizard, Shifu Wang, Jie Ding, Xiong Zhang, Wen-Yang Huang, Wen-Jing Zeng, Chengyu Liu, Yanguang Li, Sung-Fu Hung, Yanqiang Huang, Marc Robert, Bin Liu

Publikováno v: Nature Communications, Vol 14, Iss 1, Pp 1-10 (2023)

Abstract While exploring the process of CO/CO2 electroreduction (COxRR) is of great significance to achieve carbon recycling, deciphering reaction mechanisms so as to further design catalytic systems able to overcome sluggish kinetics remains challen

Externí odkaz: https://doaj.org/article/84a40651dfe44c338b8924fd1028e5e0

Selectivity control of CO versus HCOO− production in the visible-light-driven catalytic reduction of CO2 with two cooperative metal sites

Autor: Zhenguo Guo, Claudio Cometto, Hongbo Fan, Gui Chen, Kai-Chung Lau, Bing Ma, Thomas Groizard, Hongyan Zhao, Lingjing Chen, Wai-Lun Man, Tai-Chu Lau, Marc Robert, Shek-Man Yiu

Publikováno v: Nature Catalysis. 2:801-808

It is highly desirable to discover molecular catalysts with controlled selectivity for visible-light-driven CO2 reduction to fuels. In the design of catalysts employing earth-abundant metals, progress has been made for CO production, but formate gene

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::72639f2cc4b40001bd87e763bbccc753
https://doi.org/10.1038/s41929-019-0331-6

1,4-Diethynylbenzene-Bridged [Cp*(dppe)Fe](n+) Units: Effect of 2,5-Ethynyl Groups on the Chemical and Electronic Properties

Autor: Jean-René Hamon, Jean-François Halet, Vincent Dorcet, Samia Kahlal, Thierry Roisnel, Thomas Groizard, Rim Makhoul, Paul Hamon, Claude Lapinte

Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2020, 2020 (27), pp.2624-2638. ⟨10.1002/ejic.202000345⟩
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2020, 2020 (27), pp.2624-2638. ⟨10.1002/ejic.202000345⟩

International audience; The bis(ironvinylidene) complex [1,4-{Cp*(dppe)Fe=C=CH}(2)-2,5-(C equivalent to CH)(2)-C6H2](PF6)(2) ([2-2H](PF6)(2)) was prepared from 1,2,4,5-tetraethynylbenzene and two equiv. of Cp*(dppe)FeCl in 87 % yield. The reaction is

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4326f7315e26aeaa72ec62cdb5405d55
https://hal.science/hal-02886406/document

Theoretical studies of mixed-valence organometallic species for potential utilization as quantum cellular automata

Autor: Samia Kahlal, Jean-François Halet, Thomas Groizard

Publikováno v: Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, Elsevier, 2017, 844, pp.35-42. ⟨10.1016/j.jorganchem.2017.02.021⟩
Journal of Organometallic Chemistry, 2017, 844, pp.35-42. ⟨10.1016/j.jorganchem.2017.02.021⟩

International audience; The chemistry of mixed-valence complexes joins that of molecular electronics in the quantum cellular automata (QCA) paradigm, a concept which has been demonstrated to be a possible alternative to the transistor-based technolog

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::49a1ea07d288a5da565f739bb5fdbd4f
https://doi.org/10.1016/j.jorganchem.2017.02.021

Enhanced Cooperativity in Supported Spin-Crossover Metal-Organic Frameworks

Autor: Thomas Groizard, Mikael Kepenekian, Nick Rübner Papior, Boris Le Guennic, Vincent Robert

Publikováno v: Dipòsit Digital de Documents de la UAB
Universitat Autònoma de Barcelona
Recercat. Dipósit de la Recerca de Catalunya
instname
Journal of Physical Chemistry Letters
Journal of Physical Chemistry Letters, American Chemical Society, 2017, 8 (14), pp.3415-3420. ⟨10.1021/acs.jpclett.7b01248⟩
Recercat: Dipósit de la Recerca de Catalunya
Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Journal of Physical Chemistry Letters, 2017, 8 (14), pp.3415-3420. ⟨10.1021/acs.jpclett.7b01248⟩

International audience; The impact of surface deposition on cooperativity is explored in Au(111)-supported self-assembled metal-organic frameworks (MOFs) based on Fe(II) ions. Using a thermodynamic model, we first demonstrate that dimensionality redu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ac3e7f078a8785425c0a97f816b88307
https://ddd.uab.cat/record/225320