Zobrazeno 1 - 10
of 28
pro vyhledávání: '"Thomas G. Spence"'
Publikováno v:
2021 IEEE International Symposium on Antennas and Propagation and USNC-URSI Radio Science Meeting (APS/URSI).
Autor:
Douglas H. Werner, Thomas G Spence
Publikováno v:
IEEE Transactions on Antennas and Propagation. 58:3931-3941
The Peano-Gosper space-filling curve provides an excellent framework for designing planar antenna array distributions with modular architectures and suppressed sidelobes over a relatively wide bandwidth. The curve consists of a self-avoiding path tha
Autor:
Charles C. Harb, Paul J. Dagdigian, Thomas G. Spence, Karl David Pavey, Toby K. Boyson, David S. Moore, Nicholas John Fitzgerald
Publikováno v:
Optics letters. 40(19)
Cavity-enhanced spectroscopy is a sensitive optical absorption technique but one where the practical applications have been limited to studying small wavelength ranges. This Letter shows that wideband operation can be achieved by combining techniques
Autor:
Robert Provencal, Michael W. Todd, Jessica Glasser, Bruce A. Richman, Eric R. Crosson, Kenneth N. Ricci, Barbara A. Paldus, Frank C. Chilese, and Alex A. Kachanov, Thomas Owano, Thomas G. Spence, Richard N. Zare
Publikováno v:
Analytical Chemistry. 74:2003-2007
We have constructed a cavity ring-down spectrometer employing a near-IR external cavity diode laser capable of measuring 13C/12C isotopic ratios in CO2 in human breath. The system, which has a demonstrated minimum detectable absorption loss of 3.2 x
Autor:
Robert L. Byer, Benno Willke, Richard N. Zare, Thomas G. Spence, Charles C. Harb, Barbara A. Paldus
Publikováno v:
Review of Scientific Instruments. 71:347-353
A system is described that employs a diode-pumped Nd:YAG continuous-wave laser source servolocked to a three-mirror optical cavity and an analog detection circuit that extracts the ring-down rate from the exponentially decaying ring-down waveform. Th
Autor:
Thomas G. Spence, H. A. Schwettman, Eric R. Crosson, P. Haar, Barbara A. Paldus, G. A. Marcus, Richard N. Zare
Publikováno v:
Review of Scientific Instruments. 70:4-10
Pulse stacking, or synchronous pumping, is a novel approach that offers important advantages in cavity ring-down spectroscopy. Using an ultrashort pulse, high repetition rate laser source we have shown that it is possible to resonantly stack pulses i
Publikováno v:
The Journal of Physical Chemistry A. 102:7779-7786
The first direct measurements of the contributions of individual solvent molecules to solvent reorganization associated with photoinitiated charge transfer in a coordination complex are reported fo...
Publikováno v:
International Journal of Mass Spectrometry. 177:187-196
Photochemistry resulting from excitation of a d–d transition at 575 nm between ligand-field states in the gas-phase [CuII(bpy)(serine–H)]+ · complex generated by electrospray ionization is reported. These results are discussed in terms of a reac
Autor:
Barbara A. Paldus, Richard N. Zare, Marc D. Levenson, Thomas G. Spence, James S. Harris, Charles C. Harb
Publikováno v:
Chemical Physics Letters. 290:335-340
Polarization-selective optical heterodyne detection is shown to enhance the practical sensitivity of cavity ring-down spectroscopy. Initial experiments demonstrate a signal-to-noise ratio above 31 dB. Minor improvements should yield shot-noise-limite
Publikováno v:
The Journal of Physical Chemistry A. 102:6101-6106
The solvent dependence of metal-to-ligand charge transfer (MLCT) in the bis(2,2‘,2‘‘-terpyridyl)iron(II) complex, [Fe(terpy)2]2+, isolated in small gas-phase clusters with one or four molecules of the polar, organic solvents acetone, acetonitri