Zobrazeno 1 - 10
of 82
pro vyhledávání: '"Thomas G. Richmond"'
Autor:
Thomas G. Richmond
Publikováno v:
Angewandte Chemie. 39:3241-3244
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3b9b30e1d6271e4724f976c40ef99c8b
https://doi.org/10.1002/1521-3773(20000915)39:18<3241::aid-anie3241>3.0.co
https://doi.org/10.1002/1521-3773(20000915)39:18<3241::aid-anie3241>3.0.co
Preparation of molybdenum(II) η2-vinyl complexes via sequential CCl activation and alkyne insertion
Publikováno v:
Polyhedron. 16:409-415
Reaction of the Schiff base ligand 1, prepared by the condensation of 2-chlorobenzaldehyde and N,N-dimethylethylenediamine with (η6-C6H5CH3)Mo(CO)3 2 resulted in the formation of the seven-coordinate molybdenum(II) metallacycle, 3, by oxidative addi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aa4541d41450eb46f2916a9b9dfdc6b5
https://doi.org/10.1016/0277-5387(96)00311-7
https://doi.org/10.1016/0277-5387(96)00311-7
Publikováno v:
Organometallics. 16:246-254
This work describes the synthesis, structures, and reactivity studies of a series of novel η2-nitrile and η2-alkyne complexes in which the sidebound nitrile and alkyne ligands serve as four-electron donor ligands. In these tungsten(II) carbonyl flu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7d9a9b4c116482c396e76c9207ab99e1
https://doi.org/10.1021/om960974t
https://doi.org/10.1021/om960974t
Autor:
Thomas G. Richmond, Greg Owens
Publikováno v:
The Chemical Educator. 1:1-4
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d53a18bb1e6fd977e3a2a21888eb350d
https://doi.org/10.1007/s00897960045a
https://doi.org/10.1007/s00897960045a
Autor:
Jaqueline L. Kiplinger, Rudi van Eldik, Atta M. Arif, ‡ and Carlos Dücker-Benfer, Thomas G. Richmond
Publikováno v:
Organometallics. 15:1545-1564
This report describes a novel migratory insertion reaction which leads to the formation of highly fluorinated η2-vinyl complexes at a tungsten(II) metal center. Insight into the nature of this transformation was obtained by isolation and crystallogr
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::567a38bbe95d636e714f5d0047d9ea7c
https://doi.org/10.1021/om9509251
https://doi.org/10.1021/om9509251
Autor:
Steven D. Looman, Thomas G. Richmond
Publikováno v:
Inorganica Chimica Acta. 240:479-484
Two methods are described to derivatize silica with tethered tungsten(II) complexes. One method constructs the desired aryl halide ligand on the silica surface followed by oxidative addition using a source of ‘W(CO)3’. The second method involves
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fc6f57c2e0a2e83044105015e53efc2e
https://doi.org/10.1016/0020-1693(95)04572-4
https://doi.org/10.1016/0020-1693(95)04572-4
Publikováno v:
Chemical Reviews. 94:373-431
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dc0b2c19e04c8866abc2db9b2e3e0dc0
https://doi.org/10.1021/cr00026a005
https://doi.org/10.1021/cr00026a005
Autor:
Thomas G. Richmond
Publikováno v:
ChemInform. 22
Hydrogen bonding often plays a crucial role in the chemistry of metal complexes and is of particular importance in the interactions of coordination compounds with biological systems. This account will discuss the role of hydrogen bonding in transitio
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9478127704c7179a97a45c3548e446cb
https://doi.org/10.1002/chin.199108363
https://doi.org/10.1002/chin.199108363
Autor:
Brian P. Buffin, Thomas G. Richmond
Publikováno v:
ChemInform. 22
The reactions of a series of Schiff base ligands (1–4) prepared by condensation of pyridine-2-carboxaldehyde and 2-X-anilines (X = F, Cl, Br, OMe) with W(CO)3(RCN)3 results in the formation of deeply coloured complexes W(CO)3(1–4)(NCR) which read
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::026f497afe94392bac8e3724cb2a0dae
https://doi.org/10.1002/chin.199116226
https://doi.org/10.1002/chin.199116226
Publikováno v:
ChemInform. 22
The first examples of chelate assisted insertion of a transition metal centre into a C–F bond of mono- and di-fluoro substituted aromatic rings resulting in chelate stabilized aryl fluoride oxidative addition complexes are reported.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8bef85f102e5ebd77b8e5136c9719750
https://doi.org/10.1002/chin.199134212
https://doi.org/10.1002/chin.199134212