Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Thomas Auth"'
Publikováno v:
Chemistry – A European Journal. 28
High-valent tetraalkylcuprates(III) and -argentates(III) are key intermediates of copper and silver-mediated C-C coupling reactions. Here, we investigate the previously reported contrasting reactivity of [RM III Me 3 ] - complexes (M = Cu, Ag and R =
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bd19b46861379afee0dab97dd3439041
https://doi.org/10.1002/chem.202103130
https://doi.org/10.1002/chem.202103130
High-valent tetraalkylcuprates(III) and -argentates(III) are key intermediates of copper and silver-mediated C−C coupling reactions. Here, we investigate the previously reported contrasting reactivity of [RM III Me 3 ] − complexes (M = Cu, Ag and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5ff7f67aabb89c336cfbdd4c9cef9522
https://doi.org/10.33774/chemrxiv-2021-k9msd
https://doi.org/10.33774/chemrxiv-2021-k9msd
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(7)
High-valent tetraalkylcuprates(iii) and -argentates(iii) are key intermediates of copper- and silver-mediated C-C coupling reactions. Here, we investigate the previously reported contrasting reactivity of [RM
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::c692baf01f2ec628ecf43eb607a7c8b4
https://pubmed.ncbi.nlm.nih.gov/34773654
https://pubmed.ncbi.nlm.nih.gov/34773654
Publikováno v:
Organometallics. 39:25-33
Despite the wide use of transmetalation reactions in organic and organometallic synthesis, little is known about the involved intermediates and mechanisms. Here, we use a combination of electrospra...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ef2817e5c7fb487e4a73da442eccfa59
https://doi.org/10.1021/acs.organomet.9b00521
https://doi.org/10.1021/acs.organomet.9b00521
Autor:
Thomas Auth, Konrad Koszinowski
Publikováno v:
Journal of the American Society for Mass Spectrometry. 30:1857-1866
In contrast to the extensive knowledge of lithium cation affinities and basicities, the thermochemistry of microsolvated lithium cations is much less explored. Here, we determine the relative stabilities of Li(A,B)n+ complexes, n = 2 and 3, by monito
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5ab6237a0fede5b64a7811e38e0853b5
https://doi.org/10.1007/s13361-019-02312-5
https://doi.org/10.1007/s13361-019-02312-5
Publikováno v:
Analytical Chemistry. 91:11703-11711
Previous attempts to characterize the internal energies of ions produced by electrospray ionization (ESI) have chiefly relied upon benzylpyridinium ions, R-BnPy+, as thermometer ions. However, thes...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::30f24ea75dfbd98c004c68691fdbf54e
https://doi.org/10.1021/acs.analchem.9b02257
https://doi.org/10.1021/acs.analchem.9b02257
Publikováno v:
Analytical Chemistry
Organometallics are widely used in catalysis and synthesis. Their analysis relies heavily on mass spectrometric methods, among which traveling-wave ion mobility spectrometry (TWIMS) has gained increasing importance. Collision cross sections (CCS) obt
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9a4fa6b28d00c3045951f66e2d90cdfd
https://pubmed.ncbi.nlm.nih.gov/34227799
https://pubmed.ncbi.nlm.nih.gov/34227799
Publikováno v:
Inorganic chemistry. 59(19)
Copper(I) hydride complexes represent a promising entry into formic acid dehydrogenation catalysis. Herein we present the spontaneous decarboxylation of a μ1,3-formate-bridged dicopper(II) complex ...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4035f31ab2b6eb5e4e7330e74fdcb3e4
https://pubmed.ncbi.nlm.nih.gov/32941732
https://pubmed.ncbi.nlm.nih.gov/32941732
Autor:
Thomas Auth, Sebastian Weske, Konrad Koszinowski, Richard A. Hardin, Richard A. J. O'Hair, Craig A. Ogle
Publikováno v:
Chemical Communications. 54:5086-5089
Despite the potential of silver to mediate synthetically valuable cross-coupling reactions, the operating mechanisms have remained unknown. Here, we use a combination of rapid-injection NMR spectroscopy, electrospray-ionization mass spectrometry, and
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::aa8cc615a6d616ef0e52dab9af819cac
https://doi.org/10.1039/c8cc01707g
https://doi.org/10.1039/c8cc01707g
Autor:
Thomas Auth, Gerrit C. Groenenboom, Mark Brouard, Jolijn Onvlee, Sebastiaan Y. T. van de Meerakker, Sjoerd N. Vogels, B. Nichols, Ad van der Avoird, Tijs Karman, Sean D. S. Gordon
Publikováno v:
Nature Chemistry, 9, 226-233
Nature Chemistry, 9, 3, pp. 226-233
Nature Chemistry, 9, 3, pp. 226-233
Stereodynamics describes how the vector properties of molecules, such as the directions in which they move and the axes about which they rotate, affect the probabilities (or cross-sections) of specific processes or transitions that occur on collision
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4c9fed30770b540ea3dc0783c641da3b
https://doi.org/10.1038/nchem.2640
https://doi.org/10.1038/nchem.2640