Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Thomas A. Cripe"'
Autor:
Frederick G. Bordwell, Mark J. Bausch, Thomas H. Cripe, Mark E. Mueller, J.-P. Cheng, Tsuei Yun Lynch
Publikováno v:
The Journal of Organic Chemistry. 55:58-63
Acidite dans le DMSO d'α-arylmorpholineacetonitriles, d'α-arylpiperidineacetonitriles-1, d'α-arylcyclohexaneacetonitriles et potentiels d'oxydation de leurs bases conjuguees
Autor:
Martin J. O'Donnell, William N. Jacobsen, Keith. Knuth, William D. Bennett, Robin Polt, Frederick G. Bordwell, Thomas A. Cripe, Brigitte. LeClef, William A. Bruder, Susan Romberg Mrozack
Publikováno v:
Journal of the American Chemical Society. 110:8520-8525
Equilibrium acidities in Me2S0 are reported for six ketimines of the type Ph2C=NCH(R)C02Et and five aldimines, ArCH=NCH(R)C02Et. Changing R in the ketimine from H to Ph increased the pKa by 2.2 units. This surprising acidity decrease for Ph substitut
Publikováno v:
Israel Journal of Chemistry. 26:357-366
The rate constants for reactions of a family of 19 carbanions, ArCHSO2Ph− (derived from benzyl phenyl sulfones) with n-butyl chloride have been measured in Me2SO solution. A plot of log k vs. the pKa of the conjugate acids for 12 of these carbanion
Publikováno v:
Advances in Chemistry ISBN: 9780841209527
Nucleophilicity
Nucleophilicity
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8ca6d453d2437f22639d93e2b59fb655
https://doi.org/10.1021/ba-1987-0215.ch009
https://doi.org/10.1021/ba-1987-0215.ch009
Autor:
Frederick G. Bordwell, Thomas A. Cripe, Martin J. O'Donnell, Keith. Knuth, William N. Jacobsen, William D. Bennett, Susan Romberg Mrozack, Brigitte. LeClef, William A. Bruder, Robin Polt
Publikováno v:
ChemInform. 20
Equilibrium acidities in Me2S0 are reported for six ketimines of the type Ph2C=NCH(R)C02Et and five aldimines, ArCH=NCH(R)C02Et. Changing R in the ketimine from H to Ph increased the pKa by 2.2 units. This surprising acidity decrease for Ph substitut
Autor:
J. MILTON HARRIS, SAMUEL P. MCMANUS, John I. Brauman, James A. Dodd, Chau-Chung Han, Edward S. Lewis, Thomas A. Douglas, Mark L. McLaughlin, Richard N. McDonald, A. K. Chowdhury, W. Y. Gung, K. D. DeWitt, Marjorie C. Caserio, Jhong K. Kim, Michael Henchman, Peter M. Hierl, John F. Paulson, Takashi Ando, Takahide Kimura, Hiroshi Yamataka, Claude F. Bernasconi, Frederick G. Bordwell, Thomas A. Cripe, David L. Hughes, William P. Jencks, Calvin D. Ritchie, Shmaryahu Hoz, R. F. Hudson, Fredric M. Menger, Kaoru Fuji, Ralph G. Pearson, M. R. Sedaghat-Herati, N. Neamati-Mazraeh, M. J. Kamlet, R. M. Doherty, R. W. Taft, M. H. Abraham, T. W. Bentley, Dennis N. Kevill, Steven W. Anderson, Edward K. Fujimoto, Dan Fărcaşiu, Paul E. Peterson, Annette D. Allen, V. M. Kanagsabapathy, Thomas T. Tidwell, Addy Pross, Cristina Paradisi, Gianfranco Scorrano, Glen A. Russell, Rajive K. Khanna, E. Buncel, J. M. Dust, K. T. Park, R. A. Renfrow, M. J. Strauss, J. F. King, S. Skonieczny, K. C. Khemani, J. D. Lock, Zvi Rappoport, Clifford A. Bunton, G. W. Gokel, L. Echegoye