Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Thomas Zessin"'
Publikováno v:
Journal of Organometallic Chemistry. 714:22-31
Six new mono-substituted carbonyl clusters [M3(CO)11(DPMO)] (M = Os, Ru; 1–4) and [Rh6(CO)15(DPMO)] (5, 6) were obtained from the reactions of non-symmetrical bifunctional diphosphane monoxides (DPMOs, Ph2P(CH2)nP(O)Ph2, n = 2, 3) with triangular c
Publikováno v:
Modeling of Molecular Properties
Autor:
Tobias Adamczyk, Guang‐Ming Li, Annekathrin Seifert, Gerald Linti, Thomas Zessin, Hans Pritzkow
Publikováno v:
European Journal of Inorganic Chemistry. 2011:3480-3492
The reactions of gallium subhalides Ga2X4·2dioxane (X = Cl, Br) and “GaI” with carbonylmetallates of chromium, iron and cobalt result in the formation of various gallium halide complexes. These are [(CO)5CrGaBr(thf)2] (6), with a terminal GaX un
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 71:331-337
In the endo-conformation of the substituted cyclam derivative L, with two trans-disposed di-2-pyridylmethanamine (dipa) coordination sites (endo: both dipa subunits on the same face of cyclam), the bis-dipa-substituted cyclam platform may form hexaco
Molecular Assemblies Based on Cp*BiX2 Units (X = Cl, Br, I): An Experimental and Computational Study
Publikováno v:
Organometallics. 30:2844-2854
A series of pentamethylcyclopentadienyl-substituted bismuth halo complexes were prepared by the reactions of bismuth(III) halides BiX3 (X = Cl, Br, I) with LiCp* (Cp* = C5Me5) in 1:1 ratio. The cry...
Publikováno v:
European Journal of Inorganic Chemistry. 2010:3212-3219
The reaction of cyclo-Bi 4 [Si(SiMe 3 ) 3 ] 4 (1) with Na 2 [Fe(CO) 4 ] in the presence of nBu 4 NCl leads to the formation of the cage compound [nBu 4 N] 4 [Bi 4 Fe 8 (CO) 28 ] (2). According to X-ray single-crystal structure analysis, the faces of
Publikováno v:
European Journal of Inorganic Chemistry. 2010:322-332
On reaction of BiBr 3 with Li(thf) 3 SiPh 2 tBu (1) in the corresponding ratios redox/metathesis reactions were observed, yielding dibismuthane (tBuPh 2 Si) 4 Bi 2 (2) and disilylbismuth halide (tBuPh 2 Si) 2 BiBr (3). The latter is a reaction interm
Publikováno v:
Chemistry - A European Journal. 15:12114-12120
The gallium(I) derivative [Ga({N(dipp)CMe}(2)CH)] (1; dipp = 2,6-diisopropylphenyl) undergoes facile oxidative addition reactions with various element-hydrogen bonds including N-H, P-H, O-H, Sn-H, and H-H bonds. This was demonstrated by its reaction
Publikováno v:
Inorganic Chemistry. 52:6782-6784
We describe the synthesis and structural characterization of the unprecedented [Bi4Fe3(CO)9] cluster, the low-valent Bi atoms of which are involved in the types of previously not identified intermolecular Bi···π(arene) and ΔBi···π(arene)inte
Autor:
Gerald Linti, Thomas Zessin
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 40(20)
The neutral trigallane R(3)Ga(3)I(2) was obtained in high yields by reaction of "GaI" with the moderately sterically demanding lithium N,N'-dicyclohexylneopentylamidinate. Its chemical reactions with N-lithio-2-propanimine, sodium superhydride and el