Zobrazeno 1 - 10
of 37
pro vyhledávání: '"Thomas, Weskamp"'
Publikováno v:
Angewandte Chemie. 113:3500-3503
Autor:
Christian W. K. Gstöttmayr, Thomas Weskamp, Wolfgang A. Herrmann, Volker P. W. Böhm, Claus-Peter Reisinger, Manja Grosche
Publikováno v:
Journal of Organometallic Chemistry. :616-628
A variety of mixed palladium(II) complexes bearing N-heterocyclic carbenes (NHCs) and triaryl- and trialkylphosphines [NHC(R2)]Pd(PR′3)I2 (R=Me, t-Bu, (R)-1-phenylethyl; R′=Ph, o-tolyl, cyclohexyl, t-Bu) have been prepared. Crystal structure deta
Autor:
Oskar Nuyken, James G. Hamilton, Thomas Weskamp, Florian J. Kohl, Wolfgang A. Herrmann, Ulrich Frenzel, John J. Rooney
Publikováno v:
Journal of Organometallic Chemistry. 606:8-12
Various well-defined ruthenium alkylidene complexes bearing N-heterocyclic carbene ligands were used for the ring-opening metathesis polymerization of 7-methylnorbornene and 7-methylnorbornadiene. The influence of the ligands on the tacticity of the
Publikováno v:
Journal of Organometallic Chemistry. 600:12-22
Recently, transition-metal complexes containing nucleophilic N -heterocyclic carbenes (NHCs) have been receiving increased attention in the literature, largely due to their favorable application in homogeneous catalysis. This article reviews the prin
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 153:49-52
An oxidation system consisting of methyltrioxorhenium and H 2 O 2 catalyzes the cleavage of CC-double bonds. By varying the reaction conditions, it is possible to generate either the aldehyde or the carboxylic acid in reasonable-to-excellent yields a
Publikováno v:
Journal of Organometallic Chemistry. 595:186-190
Palladium(0) complexes of N-heterocyclic carbenes (NHC) are easily obtained starting from the free carbene and bis(tri-orthotolylphosphine)palladium(0) by ligand exchange. The complexes [(R)N(H)CC(H)N(R)C ‚„„„„„„„„„” ]2Pd of var
Publikováno v:
Angewandte Chemie. 111:2573-2576
ZweiN-heterocyclischeCarbenligandenaufeinmalsindvielleichteinerzuviel, zumindest wenn man hochaktive Rutheniumkatalysatoren fur die Olefinmetathese haben mochte. Dichtefunktionalrechnungen empfehlen den Austausch des zweiten Carbenliganden in den erf
Publikováno v:
Angewandte Chemie International Edition. 38:2416-2419
Two N-heterocyclic carbene ligands at once may be one too many, at least if you intend to have highly active ruthenium catalysts for olefin metathesis. Density functional calculations recommend the replacement of the second carbene ligand in the succ
Publikováno v:
Journal of Organometallic Chemistry. 585:348-352
Complexes of the type (NHC)Pd(PR3)I2 with bulky N-heterocyclic carbenes (NHC) are efficient catalysts for aryl coupling reactions such as the Suzuki and Stille cross-coupling reaction. These catalysts combine the advantageous stability of bis(carbene
Publikováno v:
Journal of Organometallic Chemistry. 582:362-365
Ruthenium-based catalysts for olefin metathesis have attained enormous attention during the past years. Recently we have shown that the application of N -heterocyclic carbenes extends and complements the ubiquitous phosphanes. We now report on new me