Bildung und Reaktivität eines Hydridosilikats [SiH 6 ] 2− , koordiniert an einem durch einen Makrozyklus stabilisierten Strontiumkation

Autor: Thomas Höllerhage, Priyabrata Ghana, Thomas P. Spaniol, Ambre Carpentier, Laurent Maron, Ulli Englert, Jun Okuda

Publikováno v: Angewandte Chemie. 134

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7e9e3bdadfcc9efecc9587229d20be60
https://doi.org/10.1002/ange.202115379

Strontium Hydride Cations Supported by a Large NNNNN Type Macrocycle: Synthesis, Structure, and Hydrofunctionalization Catalysis

Autor: Thomas Höllerhage, Thomas P. Spaniol, Ambre Carpentier, Laurent Maron, Jun Okuda

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, 2022, 61 (7), pp.3309-3316. ⟨10.1021/acs.inorgchem.1c03894⟩

International audience; The use of the 15-membered NNNNN macrocyclic ligand Me(5)PACP (Me(5)PACP = 1,4,7,10,13-pentamethyl-1,4,7,10,13-pentaazacyclopentadecane) allowed the isolation of two cationic strontium hydride complexes by hydrogenolysis of be

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6f18d107d00deab7ff574be011184604
https://hal.science/hal-03714655

Cationic barium benzyl and hydride complexes that contain an eighteen-membered N,N,N,N,N,N-type macrocycle

Autor: Thomas Höllerhage, Thomas P. Spaniol, Ulli Englert, Jun Okuda

Publikováno v: Inorganica Chimica Acta. 543:121198

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::411e3e41619d13dc3fe4fd8f8cdd0595
https://doi.org/10.1016/j.ica.2022.121198

Calcium Hydride Catalysts for Olefin Hydrofunctionalization: Ring-Size Effect of Macrocyclic Ligands on Activity

Autor: Danny Schuhknecht, Thomas Höllerhage, Laurent Maron, Alisha Mistry, Thomas P. Spaniol, Jun Okuda, Yan Yang

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, 2021, 27 (9), pp.3002-3007. ⟨10.1002/chem.202004931⟩
Chemistry (Weinheim an Der Bergstrasse, Germany)
Chemistry-a European journal 27(9), 3002-3007 (2021). doi:10.1002/chem.202004931

The fifteen‐membered NNNNN macrocycle Me5PACP (Me5PACP=1,4,7,10,13‐pentamethyl‐1,4,7,10,13‐pentaazacyclopentadecane) stabilized the [CaH]+ fragment as a dimer with a distorted pentagonal bipyramidal coordination geometry at calcium. The hydri

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b9eba27aea274ea3dfca1974002d5fab
https://hal.science/hal-03717259

The Nature of the Heavy Alkaline Earth Metal-Hydrogen Bond: Synthesis, Structure, and Reactivity of a Cationic Strontium Hydride Cluster

Autor: Thomas P. Spaniol, Jun Okuda, Thomas Höllerhage, Debabrata Mukherjee, Valeri Leich, Laurent Maron, Ulli Englert

Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, 2018, 140 (9), pp.3403-3411. ⟨10.1021/jacs.7b13796⟩

International audience; The molecular strontium hydride [(Me(3)TACD)(3)Sr-3(mu(3)-H)(2)][SiPh3] (2) was isolated as the dark red benzene solvate 2 center dot C6H6 in 69% yield from the reaction of [Sr(SiPh3)(2)(thf)(3)] (1') with (Me(3)TACD)H (1,4,7-

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e25b854bf4e7d8a68540435be70b141
https://hal.science/hal-04037750