Zobrazeno 1 - 9
of 9
pro vyhledávání: '"Thilina, Gunasekara"'
Autor:
Thilina Gunasekara, Yicheng Tong, Amy L. Speelman, Jeremy D. Erickson, Aaron M. Appel, Michael B. Hall, Eric S. Wiedner
Publikováno v:
ACS Catalysis. 12:2729-2740
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4b48817376f1b236f5a70116ba78eee4
https://doi.org/10.1021/acscatal.1c05509
https://doi.org/10.1021/acscatal.1c05509
Autor:
R. Morris Bullock, Amy L. Speelman, Benjamin D. Neisen, Ba L. Tran, Thilina Gunasekara, Eric S. Wiedner
Publikováno v:
Angewandte Chemie International Edition. 59:8645-8653
We report mechanistic studies on the insertion reactions of [(NHC)Cu(μ-H)]2 complexes with carbonyl substrates by UV-vis and 1 H NMR spectroscopic kinetic studies, H/D isotopic labelling, and X-ray crystallography. The results of these comprehensive
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::439c044ab9b4c29eee1ec3e7d2c99815
https://doi.org/10.1002/anie.201916406
https://doi.org/10.1002/anie.201916406
Publikováno v:
2022 2nd International Conference on Advanced Research in Computing (ICARC).
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::fb0a0285b181ed14d9e90b0f2d340688
https://doi.org/10.1109/icarc54489.2022.9754086
https://doi.org/10.1109/icarc54489.2022.9754086
Autor:
Jack R. Norton, Thilina Gunasekara, Andreas Hansen, Fabian Bohle, Jonathan L. Kuo, Hunter B. Vibbert, Stefan Grimme, Patrick J. Quinlivan
Publikováno v:
Organometallics. 38:4319-4328
Hydrogen atom (H•) donors generated from H2 facilitate the atom efficient reduction of small molecule substrates. However, generating H• donors with X–H bond dissociation free energies (BDFEs) belo...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::727bd881712021a59b7f117f60ca2e6d
https://doi.org/10.1021/acs.organomet.9b00586
https://doi.org/10.1021/acs.organomet.9b00586
Autor:
Hagen Neugebauer, Andreas Hansen, Stefan Grimme, Thilina Gunasekara, Markus Bursch, Jack R. Norton, Graham P. Abramo
Publikováno v:
Journal of the American Chemical Society. 141:1882-1886
We have demonstrated the ability of TEMPO to catalyze H· transfer from (C5Ph5)Cr(CO)3H to a trityl radical (tris(p-tert-butylphenyl)methyl radical). We have measured the rate constant and activatio...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b2cb6bcf9687e18947f6de809d86cbd2
https://doi.org/10.1021/jacs.8b12892
https://doi.org/10.1021/jacs.8b12892
Publikováno v:
Journal of the American Chemical Society. 140:8980-8989
The 2,3-dimethylbutadiene complexes of Group 4 metals with constrained geometry (cg) ligands have been prepared and found to adopt a supine orientation with σ2,π bonding. Treatment of cgTi(2,3-dimethylbutadiene) (1-Ti) with tBuNC leads to the forma
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d02deec3b070166a408bce992de046d3
https://doi.org/10.1021/jacs.8b05377
https://doi.org/10.1021/jacs.8b05377
Autor:
Andrew Z. Preston, Mahdi M. Abu-Omar, Silei Xiong, D. Keith Steelman, W. Nicholas Delgass, Thilina Gunasekara, Grigori A. Medvedev, Jungsuk Kim, James M. Caruthers
Publikováno v:
Macromolecules. 50:9151-9161
A zirconium amine bis(phenolate) catalyst that is capable of simultaneously producing both oligomers and polymers of 1-hexene was investigated. It was found that the polymer produced has more branching than the commonly encountered poly(1-hexene), su
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::492e7db498fcea2379baf1612ae15c44
https://doi.org/10.1021/acs.macromol.7b01341
https://doi.org/10.1021/acs.macromol.7b01341
Publikováno v:
Organometallics. 36:2934-2939
Five new structural analogues of a previously studied group IV amine bis(phenolate) catalyst, Zr(ONNEt2O)Bn2, have been synthesized and tested for oligomerization activity. These structural variations encompass longer alkyl groups, propyl and butyl,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ca968cf7e7356078b340d1db46606182
https://doi.org/10.1021/acs.organomet.7b00359
https://doi.org/10.1021/acs.organomet.7b00359
Autor:
Thilina, Gunasekara, Graham P, Abramo, Andreas, Hansen, Hagen, Neugebauer, Markus, Bursch, Stefan, Grimme, Jack R, Norton
Publikováno v:
Journal of the American Chemical Society. 141(5)
We have demonstrated the ability of TEMPO to catalyze H· transfer from (C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::5369bc8323051175eaedf8fd040c8fac
https://pubmed.ncbi.nlm.nih.gov/30669845
https://pubmed.ncbi.nlm.nih.gov/30669845