Zobrazeno 1 - 10
of 36
pro vyhledávání: '"Thibault Cheisson"'
Autor:
Ekaterina Lapsheva, Qiaomu Yang, Thibault Cheisson, Pragati Pandey, Patrick J. Carroll, Michael Gau, Eric J. Schelter
Publikováno v:
Inorganic Chemistry. 62:6155-6168
Autor:
Henry H. Wilson, Xiaojuan Yu, Thibault Cheisson, Patrick W. Smith, Pragati Pandey, Patrick J. Carroll, Stefan G. Minasian, Jochen Autschbach, Eric J. Schelter
Publikováno v:
Journal of the American Chemical Society.
Complexes featuring lanthanide-ligand multiple bonds are rare and highly reactive. They are important synthetic targets to understand 4f/5d-bonding in comparison to d-block and actinide congeners. Herein, the isolation and characterization of a bridg
Autor:
Alexander B. Weberg, Subhajyoti Chaudhuri, Thibault Cheisson, Christian Uruburo, Ekaterina Lapsheva, Pragati Pandey, Michael R. Gau, Patrick J. Carroll, George C. Schatz, Eric J. Schelter
Publikováno v:
Chemical science. 13(23)
The separation and purification of niobium and tantalum, which co-occur in natural sources, is difficult due to their similar physical and chemical properties. The current industrial method for separating Ta/Nb mixtures uses an energy-intensive proce
Autor:
Robert F. Higgins, Eric J. Schelter, Bren E. Cole, Joshua J. M. Nelson, Thibault Cheisson, Michael R. Gau, Patrick J. Carroll
Publikováno v:
ACS Sustainable Chemistry & Engineering. 8:14786-14794
Rare earth metal complexes of the proligand H3TriNOx ([(2-tBuNOH)C6H3CH2]3N) have been shown to afford separations of simple mixtures of rare earth metal salts. In particular, separations systems w...
Autor:
John K. Gibson, E. Varathan, Georg Schreckenbach, Wayne W. Lukens, Rebecca L. Davis, Eric J. Schelter, Thibault Cheisson, Jiwen Jian, Tian Jian
Publikováno v:
Physical Chemistry Chemical Physics. 22:12403-12411
The anions pertechnetate, TcO4-, and perrhenate, ReO4-, exhibit very similar chemical and physical properties. Revealing and understanding disparities between them enhances fundamental understanding of both. Electrospray ionization generated the gas-
Autor:
Thibault Cheisson, Bren E. Cole, Eric J. Schelter, Brian C. Manor, Robert F. Higgins, Patrick J. Carroll
Publikováno v:
Angewandte Chemie. 132:1867-1872
The separation of rare-earth ions from one another is challenging due to their chemical and physical similarities. Nearly all rare-earth separations rely upon small changes in ionic radii to direct speciation or reactivity. Herein, we show that the i
Autor:
Robert F. Higgins, Brian C. Manor, Eiko Nakamaru-Ogiso, Thibault Cheisson, Eric J. Schelter, Bren E. Cole, Patrick J. Carroll
Publikováno v:
Inorganic Chemistry. 59:172-178
Separation of the rare-earth (RE) elements (Sc, Y, La-Lu) is challenging because of their similar chemical properties, but is necessary for their applications in renewable energy and electronic device technologies. The development of separation proce
Autor:
Thibault Cheisson, Kyle D. Kersey, Nolwenn Mahieu, Patrick J. Carroll, Michael R. Gau, Alex McSkimming, Eric J. Schelter
Publikováno v:
Journal of the American Chemical Society. 141:9185-9190
A series of thorium(IV)-imido complexes was synthesized and characterized. Extensive experimental and computational comparisons with the isostructural cerium(IV)-imido complexes revealed a notably more covalent bonding arrangement for the Ce═N bond
Autor:
Eric J. Schelter, Thibault Cheisson
Publikováno v:
Science. 363:489-493
The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical similarities as a group, while individually expressing distinctive and varied electronic properties. These atomistic electronic properties are extraordinarily useful a
Publikováno v:
ACS Sustainable Chemistry & Engineering. 7:4993-5001
Phosphoryl ligands of the general formula O═PR3 (R = Me, OMe, Et, nBu, Ph, iPr, NMe2) were coordinated to [Nd(TriNOx)] (TriNOx3– = ([(2-tBuNO)C6H4CH2]3N)3–), and the resulting complexes were characterized. Solution equilibrium constants for eac