Zobrazeno 1 - 10
of 39
pro vyhledávání: '"Thibault, Cheisson"'
Autor:
Ekaterina Lapsheva, Qiaomu Yang, Thibault Cheisson, Pragati Pandey, Patrick J. Carroll, Michael Gau, Eric J. Schelter
Publikováno v:
Inorganic Chemistry. 62:6155-6168
Autor:
Henry H. Wilson, Xiaojuan Yu, Thibault Cheisson, Patrick W. Smith, Pragati Pandey, Patrick J. Carroll, Stefan G. Minasian, Jochen Autschbach, Eric J. Schelter
Publikováno v:
Journal of the American Chemical Society.
Complexes featuring lanthanide-ligand multiple bonds are rare and highly reactive. They are important synthetic targets to understand 4f/5d-bonding in comparison to d-block and actinide congeners. Herein, the isolation and characterization of a bridg
Autor:
Corwin H. Booth, Ekaterina Lapsheva, Thibault Cheisson, Patrick J. Carroll, Alex McSkimming, Eric J. Schelter, Yusen Qiao, Liane M. Moreau, Qiaomu Yang
Publikováno v:
Inorganic Chemistry Frontiers. 8:934-939
The coordination chemistry of glutarimide-dioxime (H3A) has been studied related to applications in uranyl sequestration from seawater and for the stabilization of early transition metals in high oxidation states. We report here that the H2A− anion
Autor:
Robert F. Higgins, Eric J. Schelter, Bren E. Cole, Joshua J. M. Nelson, Thibault Cheisson, Michael R. Gau, Patrick J. Carroll
Publikováno v:
ACS Sustainable Chemistry & Engineering. 8:14786-14794
Rare earth metal complexes of the proligand H3TriNOx ([(2-tBuNOH)C6H3CH2]3N) have been shown to afford separations of simple mixtures of rare earth metal salts. In particular, separations systems w...
Autor:
Alexander B. Weberg, Subhajyoti Chaudhuri, Thibault Cheisson, Christian Uruburo, Ekaterina Lapsheva, Pragati Pandey, Michael R. Gau, Patrick J. Carroll, George C. Schatz, Eric J. Schelter
Publikováno v:
Chemical science. 13(23)
The separation and purification of niobium and tantalum, which co-occur in natural sources, is difficult due to their similar physical and chemical properties. The current industrial method for separating Ta/Nb mixtures uses an energy-intensive proce
Autor:
John K. Gibson, E. Varathan, Georg Schreckenbach, Wayne W. Lukens, Rebecca L. Davis, Eric J. Schelter, Thibault Cheisson, Jiwen Jian, Tian Jian
Publikováno v:
Physical Chemistry Chemical Physics. 22:12403-12411
The anions pertechnetate, TcO4-, and perrhenate, ReO4-, exhibit very similar chemical and physical properties. Revealing and understanding disparities between them enhances fundamental understanding of both. Electrospray ionization generated the gas-
Autor:
Thibault Cheisson, Bren E. Cole, Eric J. Schelter, Brian C. Manor, Robert F. Higgins, Patrick J. Carroll
Publikováno v:
Angewandte Chemie. 132:1867-1872
The separation of rare-earth ions from one another is challenging due to their chemical and physical similarities. Nearly all rare-earth separations rely upon small changes in ionic radii to direct speciation or reactivity. Herein, we show that the i
Autor:
Robert F. Higgins, Brian C. Manor, Eiko Nakamaru-Ogiso, Thibault Cheisson, Eric J. Schelter, Bren E. Cole, Patrick J. Carroll
Publikováno v:
Inorganic Chemistry. 59:172-178
Separation of the rare-earth (RE) elements (Sc, Y, La-Lu) is challenging because of their similar chemical properties, but is necessary for their applications in renewable energy and electronic device technologies. The development of separation proce
Autor:
Thibault Cheisson, Kyle D. Kersey, Nolwenn Mahieu, Patrick J. Carroll, Michael R. Gau, Alex McSkimming, Eric J. Schelter
Publikováno v:
Journal of the American Chemical Society. 141:9185-9190
A series of thorium(IV)-imido complexes was synthesized and characterized. Extensive experimental and computational comparisons with the isostructural cerium(IV)-imido complexes revealed a notably more covalent bonding arrangement for the Ce═N bond
Autor:
Eric J. Schelter, Thibault Cheisson
Publikováno v:
Science. 363:489-493
The rare earths (REs) are a family of 17 elements that exhibit pronounced chemical similarities as a group, while individually expressing distinctive and varied electronic properties. These atomistic electronic properties are extraordinarily useful a