Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Theresa Hostmann"'
Publikováno v:
Chemical Science. 12:10643-10648
A general strategy to enable the formal anti-hydrozirconation of arylacetylenes is reported that merges cis-hydrometallation using the Schwartz Reagent (Cp2ZrHCl) with a subsequent light-mediated geometric isomerization at λ = 400 nm. Mechanistic de
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a50ea1833e32143235b812be7df9b734
https://doi.org/10.1039/d1sc02454j
https://doi.org/10.1039/d1sc02454j
Publikováno v:
Chemical Science
A general strategy to enable the formal anti-hydrozirconation of arylacetylenes is reported that merges cis-hydrometallation using the Schwartz Reagent (Cp2ZrHCl) with a subsequent light-mediated geometric isomerization at λ = 400 nm. Mechanistic de
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::cd2915486aa9e5f0156ac0445b856e9c
https://pubmed.ncbi.nlm.nih.gov/34447557
https://pubmed.ncbi.nlm.nih.gov/34447557
Publikováno v:
Organic letters. 21(24)
Light-enabled enantiodivergence is demonstrated in which the alkene substrate configuration is manipulated (E → Z) prior to organocatalytic reduction with a chiral thiourea and Hantzsch ester. This allows stereodivergent reduction to be regulated a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::28bb9332d5c342a10701382ea570dd2f
https://pubmed.ncbi.nlm.nih.gov/31820651
https://pubmed.ncbi.nlm.nih.gov/31820651