Zobrazeno 1 - 10
of 12
pro vyhledávání: '"Theodore E. Nalesnik"'
Publikováno v:
Journal of Molecular Catalysis. 19:303-307
Co2(CO)8 and Co4(CO)12 in benzene solution at 150 °C catalyze hydrogen transfer from either of the donors 9,10-dihydroanthracene or 9-fluorenol to the hydrogen acceptor 1,1-diphenylethylene; in the process anthracene and fluorenone are formed, respe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::287bd34d3b2aa31a327af19bad42e715
https://doi.org/10.1016/0304-5102(83)80002-9
https://doi.org/10.1016/0304-5102(83)80002-9
Publikováno v:
Journal of Organometallic Chemistry. 221:193-197
The tetrasubstituted ethylene, bifluorenylidene, reacts very rapidly (4.06 X 10−2 1 mol−1 sec−1 at 0°C) with HCo(CO)4 to give bifluorenyl. α-Phenylacrylonitrile (atroponitrile) reacts even more rapidly under the same conditions (6.0 l mol−s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::53a25370520277857c835f7acc6d1884
https://doi.org/10.1016/s0022-328x(00)89054-3
https://doi.org/10.1016/s0022-328x(00)89054-3
Publikováno v:
Inorganic and Nuclear Chemistry Letters. 13:569-575
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::cfacce1ae6ad60c5439dd2ddfa5352c0
https://doi.org/10.1016/0020-1650(77)80122-0
https://doi.org/10.1016/0020-1650(77)80122-0
Publikováno v:
Journal of Organometallic Chemistry. 236:95-100
The results of a study of the reactions of HCo(CO)4 and HMn(CO)5 with a variety of a substituted cyclopropenes are consistent with the formation of the intermediate caged radical pairs; recombination in the cage of the radical pair leads to hydroform
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::468855706977640727a34f318b48bc63
https://doi.org/10.1016/s0022-328x(00)86753-4
https://doi.org/10.1016/s0022-328x(00)86753-4
Publikováno v:
Inorganic and Nuclear Chemistry Letters. 13:523-527
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::657cabdcf93a99132fa9ecfb9883dfe3
https://doi.org/10.1016/0020-1650(77)80022-6
https://doi.org/10.1016/0020-1650(77)80022-6
Autor:
Theodore E. Nalesnik, Milton Orchin
Publikováno v:
Journal of Organometallic Chemistry. 222:C5-C8
We report here the first example of a stoichiometric hydroformylation using HMn(CO) 5 . Treatment of a hexane solution of 1,2-diphenyl-3,3-dimethylcyclopropene with HMn(CO) 5 at 55°C gave after 5 h a 27% yield of aldehydes, 87% cis and 13% trans . T
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8d5faccdd88edd2f0a03149df7de9422
https://doi.org/10.1016/s0022-328x(00)89027-0
https://doi.org/10.1016/s0022-328x(00)89027-0
Autor:
Theodore E. Nalesnik, Milton Orchin
Publikováno v:
Journal of Organometallic Chemistry. 199:265-269
9-Methylideneflourene (IIa) reacts rapidly with HCo(CO)4 at -67° C to give a quantitative yield of 9-methylfluorene (IIIa); k2 (13.4 ± 0.5) × 10-2 l mol-1 S-1. Although the internal olefin, 9-ethylidenefluorene (IIb) reacts more slowly than II
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5d462bffe5c9bfc4e2817a7b560c9314
https://doi.org/10.1016/s0022-328x(00)83858-9
https://doi.org/10.1016/s0022-328x(00)83858-9
Publikováno v:
Journal of Coordination Chemistry. 12:157-162
Several new transition metal complexes of the cyclopentadienyl ylides (CpPPh3, CpSMe2, and CpPy are reported. Reactions of CpSMe2 with MnCl2, FeCl2, CoCl2 and NiX2 (where X=d or Br) leads to complexes in which the ylide:metal halide stoichiometry is
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bb45c93807879114a9845f125c16212c
https://doi.org/10.1080/00958978308073844
https://doi.org/10.1080/00958978308073844
Publikováno v:
Journal of Molecular Catalysis. 16:43-49
Rate data for the stoichiometric radical hydrogenation of four conjugated aromatic olefins with HCo(CO)4 and DCo(CO)4 were obtained and the activation parameters deterimined. The kinetic isotope effect, kHkD, varied from 0.43 with ethylidenefluorene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::553fec34ec08e3eabe9d676319b03b74
https://doi.org/10.1016/0304-5102(82)80062-x
https://doi.org/10.1016/0304-5102(82)80062-x
Autor:
Theodore E. Nalesnik, Norman L. Holy
Publikováno v:
The Journal of Organic Chemistry. 42:372-374
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3d23e7c88c577183359ae22464a7a272
https://doi.org/10.1021/jo00422a053
https://doi.org/10.1021/jo00422a053