Zobrazeno 1 - 10
of 82
pro vyhledávání: '"Theodore A, Betley"'
Autor:
Dinesh Bista, Alexander P. Aydt, Kevin J. Anderton, Daniel W. Paley, Theodore A. Betley, Arthur C. Reber, Vikas Chauhan, Amymarie K. Bartholomew, Xavier Roy, Shiv N. Khanna
Publikováno v:
Journal of the American Chemical Society. 144:5172-5179
Quantum confinement in small symmetric clusters leads to the bunching of electronic states into closely packed shells, enabling the classification of clusters with well-defined valences as superatoms. Like atoms, superatomic clusters with filled shel
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3e68767e7d873f7ee1af7db4ffad4992
https://doi.org/10.1021/jacs.2c00731
https://doi.org/10.1021/jacs.2c00731
Autor:
Cristin E. Juda, Wei Bu, Yu-Sheng Chen, Kevin J. Anderton, Theodore A. Betley, Rebecca A. Musgrave, Amymarie K. Bartholomew, Su-Yin Wang, Yuyang Dong
Publikováno v:
Chemical Science
In polynuclear biological active sites, multiple electrons are needed for turnover, and the distribution of these electrons among the metal sites is affected by the structure of the active site. However, the study of the interplay between structure a
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5764cb5b9908d19aa6238beda34528b2
http://europepmc.org/articles/PMC8654065
http://europepmc.org/articles/PMC8654065
Publikováno v:
J Am Chem Soc
We report that exposing the dipyrrin complex ((EMind)L)Cu(N(2)) to air affords rapid, quantitative uptake of O(2) in either solution or the solid-state to yield ((EMind)L)Cu(O(2)). The air and thermal stability of ((EMind)L)Cu(O(2)) is unparalleled i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1e023d6565990d4b0de081a21145aa43
https://doi.org/10.1021/jacs.1c10254
https://doi.org/10.1021/jacs.1c10254
Autor:
Brian J. Malbrecht, J. Krzystek, Joscha Nehrkorn, Carmen Herrmann, Stefan Stoll, Azar Aliabadi, Kevin J. Anderton, Stephen Hill, Karsten Holldack, Samuel M. Greer, Theodore A. Betley, Alexander Schnegg
Publikováno v:
Inorganic Chemistry. 60:4610-4622
The metal-metal-bonded molecule [Bu4N][(HL)2Fe6(dmf)2] (Fe6) was previously shown to possess a thermally isolated spin S = 19/2 ground state and found to exhibit slow magnetization relaxation below a blocking temperature of ∼5 K [J. Am. Chem. Soc.2
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::daa1d56dde3315bbca2cebd9d497b5cc
https://doi.org/10.1021/acs.inorgchem.0c03595
https://doi.org/10.1021/acs.inorgchem.0c03595
Autor:
Theodore A. Betley, Gerard J. Porter, Colton J Lund, Thomas R. Cundari, Ryan M. Clarke, Shao-Liang Zheng, Yuyang Dong
Publikováno v:
J Am Chem Soc
The trityl-substituted bisoxazoline ((TrH)BOX) was prepared as a chiral analogue to previously reported nickel dipyrrin system capable of ring-closing amination catalysis. Ligand metallation with divalent NiI(2)(py)(4) followed by potassium graphite
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1bb87c2afeb3cb8cdc720d375615a0bb
https://doi.org/10.1021/jacs.0c09839
https://doi.org/10.1021/jacs.0c09839
Publikováno v:
Dalton Transactions. 50:6418-6422
Several first-row transition metal complexes of the 1,9-bis(2',4',6'-triphenylphenyl)-5-mesityl dipyrrinato ligand and its tetrahalogenated analogues have been synthesized and their luminescence spectra obtained. The protonated ligands, as well as th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b767e45259036c88e00e0acf8493511d
https://doi.org/10.1039/d1dt00945a
https://doi.org/10.1039/d1dt00945a
Publikováno v:
J Am Chem Soc
A dipyrrin-supported nickel catalyst ((AdF)L)Ni(py) ((AdF)L: 1,9-di(1-adamantyl)-5-perfluorophenyldipyrrin; py: pyridine) displays productive intramolecular C−H bond amination to afford N−heterocyclic products using aliphatic azide substrates. Th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b82eb7b9120f7eee837545f14f8fefb7
https://doi.org/10.1021/jacs.0c02126
https://doi.org/10.1021/jacs.0c02126
Autor:
Yunjung Baek, Theodore A. Betley
Publikováno v:
Angew Chem Int Ed Engl
The reactivity of ((Tr)L)Co ((Tr)L = 5-mesityl-1,9-(trityl)dipyrrin) toward various aryl azides was examined to elucidate the electronic structure and reactivity of dipyrrinato cobalt aryl nitrenoid complexes. Herein, we demonstrate the synthesis of
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::812b4901d6a8220d5d1387ced1813010
https://doi.org/10.1002/ange.202115437
https://doi.org/10.1002/ange.202115437
Autor:
Theodore A. Betley, Shao-Liang Zheng, James T. Lukens, Diana A. Iovan, Kurtis M. Carsch, Kyle M. Lancaster, Ida M. DiMucci
Publikováno v:
J Am Chem Soc
Dicopper complexes templated by dinucleating, pacman dipyrrin ligand scaffolds ((Mes)dmx, (tBu)dmx: dimethylxan-thine-bridged, cofacial bis-dipyrrin) were synthesized by deprotonation/metalation with mesitylcopper (CuMes; Mes: mesityl) or by transmet
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4452b13fa8a02b0523f03123cafecc0c
https://doi.org/10.1021/jacs.9b09616
https://doi.org/10.1021/jacs.9b09616
Publikováno v:
Chem Commun (Camb)
The effect of metal identity, d-electron count, and coordination geometry on the electronic structure of a metal-ligand multiple bond (MLMB) is an area of active exploration. Although high oxidation state Cr imido have been extensively studied, very
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a7de4201e5119724c12a7fabe8ad3703
https://doi.org/10.1039/d0cc00108b
https://doi.org/10.1039/d0cc00108b