Zobrazeno 1 - 10
of 82
pro vyhledávání: '"Thayalan, Rajeshkumar"'
Autor:
Xiaoqing Xin, Iskander Douair, Thayalan Rajeshkumar, Yue Zhao, Shuao Wang, Laurent Maron, Congqing Zhu
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-9 (2022)
The synthesis and isolation of uranium(VI) nitride complexes remains challenging. Here, the authors report an example of transition metal (TM) stabilized U(VI) nitride complexes, generated via photolysis of azide-bridged U(IV)-TM precursors.
Externí odkaz:
https://doaj.org/article/965210c08c66401b8ba2c859ca26eafb
Autor:
Xue-Lin Dai, Jingdi Ran, Thayalan Rajeshkumar, Zhengping Xu, Shanshan Liu, Zongchao Lv, Laurent Maron, Yi-Hung Chen
Publikováno v:
Organic Letters. 25:3060-3065
Autor:
K. Yuvaraj, Jeremy C. Mullins, Thayalan Rajeshkumar, Iskander Douair, Laurent Maron, Cameron Jones
Publikováno v:
Chemical Science. 14:5188-5195
The reductive tetramerisation of CO by Lewis base activated dimagnesium(i) compounds, in the presence of Mo(CO)6, led to the competitive formation of magnesium squarate and metallo-ketene complexes (see picture).
Publikováno v:
Organic Letters. 25:163-168
Herein we report the first catalytic decarbonylation and decarbonylative hydroamination of formamides without using additives enabled by a redox-neutral rare earth catalyst. The protocol displays complete
Autor:
Nikolaos Tsoureas, Thayalan Rajeshkumar, Oliver P. E. Townrow, Laurent Maron, Richard A. Layfield
Publikováno v:
Inorganic Chemistry
Inorganic Chemistry, 2022, 61 (50), pp.20629-20635. ⟨10.1021/acs.inorgchem.2c03534⟩
Inorganic Chemistry, 2022, 61 (50), pp.20629-20635. ⟨10.1021/acs.inorgchem.2c03534⟩
Cyclobutadienyl complexes of the f-elements are a relatively new yet poorly understood class of sandwich and half-sandwich organometallic compounds. We now describe cyclobutadienyl transfer reactions of the magnesium reagent [(η4-Cb'''')Mg(THF)3] (1
Autor:
Dongjing Hong, Thayalan Rajeshkumar, Shan Zhu, Zeming Huang, Shuangliu Zhou, Xiancui Zhu, Laurent Maron, Shaowu Wang
Publikováno v:
Science China Chemistry
Science China Chemistry, 2023, 66 (1), pp.117-126. ⟨10.1007/s11426-022-1396-x⟩
Science China Chemistry, 2023, 66 (1), pp.117-126. ⟨10.1007/s11426-022-1396-x⟩
International audience; Ligands play a key role in controlling activity of organometallic complexes so that development of new ligands to overcome the challenge is the main topic of modern chemistry. The first example of 1,1-hydride migratory inserti
Autor:
Donna A. Chen, Juan D. Jimenez, Sanjaya D. Senanayake, Julian P. Stetzler, Deependra M. Shakya, Gavin A. McCarver, Thayalan Rajeshkumar, Konstantinos D. Vogiatzis, Abhijai Mathur, Natalia B. Shustova, Michael L. Myrick, Kamolrat Metavarayuth, Michael M. Royko, Jochen Lauterbach, Gregory L. Tate, John R. Monnier
Publikováno v:
The Journal of Physical Chemistry C. 126:11553-11565
Publikováno v:
Chemistry – A European Journal.
The activation of dinitrogen (N2) by transition metals is central to the highly energy intensive, heterogenous Haber-Bosch process. Considerable progress has been made towards more sustainable homogeneous activations of N2 with d- and f-block metals,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::55d1e8fff3c4cadf70319515c325642d
https://doi.org/10.26434/chemrxiv-2023-6gl3t
https://doi.org/10.26434/chemrxiv-2023-6gl3t
Autor:
R. A. Keerthi Shivaraam, Megan Keener, Dieuwertje K. Modder, Thayalan Rajeshkumar, Ivica Živković, Rosario Scopelliti, Laurent Maron, Marinella Mazzanti
Publikováno v:
Angewandte Chemie International Edition. 62
Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migr