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Autor:
Thamyres S. Araujo, Maria G. F. Vaz, Samira G. Reis, Rafael A. Allão Cassaro, Paul M. Lahti, Miguel A. Novak
Publikováno v:
Inorganic chemistry. 54(19)
Two isostructural 1D complexes, [M(hfac)2NaphNN]n [M = Mn(II) (1) or Co(II) (2); NaphNN = 1-naphthyl nitronylnitroxide], were synthesized and exhibit very strong antiferromagnetic metal-radical exchange coupling. Compound 2 shows slow magnetic relaxa