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pro vyhledávání: '"Thais Delgado-Abad"'
Autor:
Javier Reig-López, María Elena González-Núñez, Thais Delgado-Abad, Gregorio Asensio, Jaime Martínez-Ferrer, Rossella Mello, Rafael Acerete
Publikováno v:
RSC Adv.. 4:51016-51021
Supercritical carbon dioxide (scCO2), a solvent with a zero dipole moment, low dielectric constant, and no hydrogen bonding behavior, is a suitable medium to perform the uncatalyzed electrophilic bromination of weakly activated aromatics with no inte
Autor:
Andrea Olmos, Rossella Mello, Ana Caballero, Gregorio Asensio, Jaime Martínez-Ferrer, Pedro J. Pérez, María Elena González-Núñez, Thais Delgado-Abad
Publikováno v:
Angewandte Chemie. 125:13540-13543
as the leaving groupdeparts from the carbon atom prior to the entrance of thenucleophile. Polar protic solvents with high dielectric con-stants promote polar bond heterolysis by providing effectiveH-bonding and electron-pair donation interactions to