Rotaxane‐Functionalized Dyes for Charge‐Rectification in p‐Type Photoelectrochemical Devices

Autor: Tessel Bouwens, Tijmen M. A. Bakker, Kaijian Zhu, Annemarie Huijser, Simon Mathew, Joost N. H. Reek

Publikováno v: Advanced Science, Vol 11, Iss 9, Pp n/a-n/a (2024)

Abstract A supramolecular photovoltaic strategy is applied to enhance power conversion efficiencies (PCE) of photoelectrochemical devices by suppressing electron–hole recombination after photoinduced electron transfer (PET). Here, the author exploi

Externí odkaz: https://doaj.org/article/93010e46d182437eb846b3a0df10854f

Palladium-catalyzed activation of H(n)A-AH(n) bonds (AH(n) = CH3, NH2, OH, F)

Autor: Bryan Phuti Moloto, Pascal Vermeeren, Marco Dalla Tiezza, Tessel Bouwens, Catharine Esterhuysen, Trevor A. Hamlin, F. Matthias Bickelhaupt

Publikováno v: Pure and Applied Chemistry, 95, 181-191
Pure and Applied Chemistry, 95, 3, pp. 181-191
Pure and Applied Chemistry, 95(3), 181-191. IUPAC Secretariat
Moloto, B P, Vermeeren, P, Tiezza, M D, Bouwens, T, Esterhuysen, C, Hamlin, T A & Bickelhaupt, F M 2023, ' Palladium-catalyzed activation of H n A-AH n bonds (AH n = CH 3, NH 2, OH, F) ', Pure and Applied Chemistry, vol. 95, no. 3, pp. 181-191 . https://doi.org/10.1515/pac-2022-1004

We have quantum chemically studied activation of HnA–AHn bonds (AHn = CH3, NH2, OH, F) by PdLn catalysts with Ln = no ligand, PH3, (PH3)2, using relativistic density functional theory at ZORA-BLYP/TZ2P. The activation energy associated with the oxi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5c9f7d375d84aba8f42d415263b2b48f
http://hdl.handle.net/2066/290977

p-Type dye-sensitized solar cells based on pseudorotaxane mediated charge-transfer

Autor: Simon Mathew, Joost N. H. Reek, Tessel Bouwens

Publikováno v: Faraday Discussions, 215, 393-406. Royal Society of Chemistry

The efficiency of p-type dye-sensitized solar cells (DSSCs) remains low compared to that of n-type congeners due to charge recombination events. We report a supramolecular approach to reduce recombination at the NiO–dye interface, realized by using

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::23f093e6e7c2ad282d1effcee2513563
https://dare.uva.nl/personal/pure/en/publications/ptype-dyesensitized-solar-cells-based-on-pseudorotaxane-mediated-chargetransfer(b3e63f09-63cc-4932-8452-b79576bd09ff).html

A Bioinspired Strategy for Directional Charge Propagation in Photoelectrochemical Devices Using Supramolecular Machinery

Autor: Tijmen M. A. Bakker, Joost N. H. Reek, Mees Dieperink, Simon Mathew, Jenny Hasenack, Tessel Bouwens

Molecular photoelectrochemical (PEC) devices are hampered by electron–hole recombination after photoinduced electron transfer (PET), causing losses in power conversion efficiency (PCE). Inspired by natural photosynthesis, we demonstrate the use of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f6529d364afe0aa2acffa4be1cb7e58e
https://doi.org/10.21203/rs.3.rs-228311/v1

Red light activation of Ru(II) polypyridyl prodrugs via triplet-triplet annihilation upconversion: feasibility in air and through meat

Autor: Iris Landman, Sven H. C. Askes, Tessel Bouwens, Michael S. Meijer, Sylvestre Bonnet

Publikováno v: MOLECULES, 21, 1460
Molecules, Vol 21, Iss 11, p 1460 (2016)
Molecules
MOLECULES
Molecules; Volume 21; Issue 11; Pages: 1460

Triplet-triplet annihilation upconversion (TTA-UC) is a promising photophysical tool to shift the activation wavelength of photopharmacological compounds to the red or near-infrared wavelength domain, in which light penetrates human tissue optimally.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::582385e0e2619002d196cd68f1f27d8f
http://hdl.handle.net/1887/46830