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Exceptionally high decarboxylation rate of a primary aliphatic acyloxy radical determined by radical product yield analysis and quantitative 1 H-CIDNP spectroscopy

Autor: Ryan Turncliff, Justin Sodano, Lev R. Ryzhkov, Alicia M. Fraind, Teri Fox

Publikováno v: Journal of Physical Organic Chemistry. 24:809-820

Symmetrical (RCO2CO2R; R = XCH2CH2) and asymmetrical (RCO2CO2R′; R = C9H19CH2CH2, R′ = CH3 or m-ClC6H4) primary diacyl peroxides were thermally decomposed under different conditions to analyze the decarboxylation rates of the thermally generated

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5b99a14eea739c3d8419ffd48a9eb842
https://doi.org/10.1002/poc.1836

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