Halide anion discrimination by a tripodal hydroxylamine ligand in gas and condensed phases

Autor: Thibault Cheisson, Jiwen Jian, Michael R. Gau, Jing Su, Patrick J. Carroll, John K. Gibson, Enrique R. Batista, Eric J. Schelter, Teresa M. Eaton, Ping Yang

Publikováno v: Physical chemistry chemical physics : PCCP, vol 21, iss 36

Electrospray ionization of solutions containing a tripodal hydroxylamine ligand, H3TriNOx ([((2-tBuNOH)C6H4CH2)3N]) denoted as L, and a hydrogen halide HX: HCl, HBr and/or HI, yielded gas-phase anion complexes [L(X)]- and [L(HX2)]-. Collision induced

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6633ca3869ae20e8d5cfc4d8ef042afe
https://doi.org/10.1039/c9cp03764k

Reductive activation of neptunyl and plutonyl oxo species with a hydroxypyridinone chelating ligand

Autor: Wibe A. de Jong, Rebecca J. Abergel, Tori Z. Forbes, Jiwen Jian, John K. Gibson, Korey P. Carter, Teresa M. Eaton, Mikaela M. Pyrch

Publikováno v: Chemical communications (Cambridge, England). 54(76)

Oxo group activation with reduction of neptunyl(vi) and plutonyl(vi) to tetravalent hydroxo species by the hydroxypyridinone siderophore derivative 3,4,3-LI-(1,2-HOPO) was investigated in the gas-phase via electrospray ionization mass spectrometry, i

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d3b2f5dd86e8d1a654c9d37620ff1d8
https://pubmed.ncbi.nlm.nih.gov/30187044

Cleaving Off Uranyl Oxygens through Chelation: A Mechanistic Study in the Gas Phase

Autor: Jonathan Martens, Ilya Captain, John K. Gibson, Wibe A. de Jong, Teresa M. Eaton, Rebecca J. Abergel, Giel Berden, Jiwen Jian, Michael J. Van Stipdonk, Jos Oomens, Gauthier J.-P. Deblonde, Phuong Diem Dau

Publikováno v: Inorganic Chemistry, 56, 21, pp. 12930-12937
Inorganic chemistry, vol 56, iss 21
Abergel, RJ; De Jong, WA; Deblonde, GJP; Dau, PD; Captain, I; Eaton, TM; et al.(2017). Cleaving off Uranyl Oxygens through Chelation: A Mechanistic Study in the Gas Phase. Inorganic Chemistry, 56(21), 12930-12937. doi: 10.1021/acs.inorgchem.7b01720. Lawrence Berkeley National Laboratory: Retrieved from: http://www.escholarship.org/uc/item/2ns7c7vs
Inorganic Chemistry, 56, 12930-12937
Inorganic Chemistry, 56(21), 12930-12937. American Chemical Society

© 2017 American Chemical Society. Recent efforts to activate the strong uranium-oxygen bonds in the dioxo uranyl cation have been limited to single oxo-group activation through either uranyl reduction and functionalization in solution, or by collisi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e737e4a6a71b1f8e018f20e331738d0c
https://hdl.handle.net/2066/180722

ChemInform Abstract: Further Evidence for the Stabilization of U(V) within a Tetraoxo Core

Autor: Teresa M. Eaton, Matthew J. Polinski, Thomas E. Albrecht-Schmitt, Jared T. Stritzinger, Justin N. Cross, Evgeny V. Alekseev

Publikováno v: ChemInform. 45

The new uranium borates K10 [(UO2)16(B2O5)2 (BO3)6O8]·7H2O (I) and K13 [(UO2)19(UO4) (B2O5)2 (BO3)6(OH)2O5] ·H2O (II) are isolated in 50% and 25% yield, resp., from reactions of UO3, KBO2, B2O3, and KOH in supercritical H2O (sealed Ag ampoules in a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::dc6da9cb92503ebc1ea8db7775f19ebd
https://doi.org/10.1002/chin.201429025

Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution

Autor: Teresa M. Eaton, Justin N. Cross, Thomas E. Albrecht-Schmitt, Jared T. Stritzinger, Jian Lin

Publikováno v: Chemical communications (Cambridge, England). 50(28)

Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu) have been prepared and characterized. Surprisingly, these compounds are isotypic and rather extreme examples of aliovalent substitution (Th(IV)vs. Ln(III); Se(IV)O3(2-)vs. I(V)O3(-)) are

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a370533a12a23b13fd312840fc8d3e84
https://pubmed.ncbi.nlm.nih.gov/24590373