Zobrazeno 1 - 10 of 58 pro vyhledávání: '"Terence V. Ashworth"'
3
Formation of cationic and neutral carbamato and related ruthenium(II) complexes from reaction of CO2, COS and CS2 with ruthenium hydrides in alcohol solution containing HNMe2. The crystal structure of [Ru(O2CNMe2)(PMe2Ph)4]PF6
Autor: Eric Singleton, Magriet J. Nolte, Terence V. Ashworth
Publikováno v: Journal of Organometallic Chemistry. 121:C57-C60
The salts [Ru(XYCR)(PMe2Ph)4]PF6 (XY = OS, R = OEt; XY = S2, R = H), [Ru(XYCNMe2)(PMe2Ph)4]PF6 (XY = O2, OS, S2) and the neutral product [RuH(O2CNMe2)(PPh3)3] are formed by interaction of CO2, COS or CS2 with [RuH(PMe2Ph)5]PF6 or [RuH2(PPh3)4] in eth
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3638832aa7179ba7b06e35de6dcebb3b
https://doi.org/10.1016/s0022-328x(00)85099-8
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4
The transition metal-catalysed reaction between Fe(CO)5 and group V donor ligands. A facile, high yield synthesis of Fe(CO)4PPh3
Autor: Terence V. Ashworth, Neil J. Coville, Eric Singleton, Michel O. Albers
Publikováno v: Journal of Organometallic Chemistry. 217:385-390
The reaction of Fe(CO) 5 and L (L = Group V donor ligand), in the presence of CoCl 2 · 2 H 2 O or CoI 2 · 4 H 2 O as catalyst, results in the synthesis of Fe(CO) 4 L in good yield. Unusual reactivity patterns for the substitution of CO on Fe(CO) 5
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::997068d8c52744980e8ecf4746207c7e
https://doi.org/10.1016/s0022-328x(00)93454-5
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5
Cationic ruthenium systems. Part 4. Bridge-splitting reactions of the triply bridged dimers bis(η-cyclo-octa-1,5-diene)(NN-dimethylhydrazine)dihalogenodihydridodiruthenium with a series of neutral donor ligands
Autor: Rolf H. Reimann, Eric Singleton, Terence V. Ashworth
Publikováno v: J. Chem. Soc., Dalton Trans.. :1036-1039
The triply bridged complexes [{RuX(H)(cod)}2(NH2NMe2)](2; X = Cl or Br; cod = cyclo-octa-1,5-diene), containing H, X, and NH2NMe2 as bridging ligands, have been prepared from [RuH(cod)(NH2NMe2)3]A (1; A = PF6 or BPh4) and LiX in moderate yields from
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::95c333875307705742d9ef35403f31e7
https://doi.org/10.1039/dt9780001036
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7
Hydrogen transfer processes in the formation of cationic η5 -dienyl complexes of ruthenium(II): X-ray structure of [Ru(1-5-η-cyclooctadienyl)(PMe2Ph)3][PF6]
Autor: Elsie Meintjies, Eric Singleton, Terence V. Ashworth, Anthony A. Chalmers, Hester E. Oosthuizen, David C. Liles
Publikováno v: Journal of Organometallic Chemistry. 284:C19-C23
The cations [Ru(1—3:5—6-η-C 8 H 11 )(η 6 -1,3,5-cyclooctatriene)] + ( 2 ) and [RuH(COD)L 3 ] + ( 5 ) (COD = cycloocta-1,5-diene, L = PMe 2 Ph, AsMePh 2 ) are convenient precursors to a range of η 5 -dienyl complexes of ruthenium(II); evidence
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::70610c00548be433f0c29590a64aa45b
https://doi.org/10.1016/0022-328x(85)80024-3
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9
Preparation of (η-cyclo-octa-1,5-diene)halogenohydridobis(phosphine)-iridium(III) salts and kinetic study of the oxidative-addition reactions of (η-cyclo-octa-1,5-diene)bis(phosphine)iridium(I) salts with hydrohalogenic acids: evidence for anionic intermediates
Autor: Joy E. Singleton, Terence V. Ashworth, Wynand J. Louw, Erwin van der Stok, Dirk J. A. de Waal, Eric Singleton
Publikováno v: J. Chem. Soc., Dalton Trans.. :340-347
The complexes [IrH(X)(cod)L2][PF6][cod = cyclo-octa-1,5-diene, X = Cl, Br, or I, L = PPh2(OMe) or PMePh2; X = Cl or Br, L = PEtPh2] and [IrHX2(cod)L](X = Br or I, L = PMePh2 or PEtPh2) have been synthesised from HX (X = Cl, Br, or I) and the salts [I
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8aa5df4a30159c6271f2e58a80430d26
https://doi.org/10.1039/dt9780000340
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10
Cationic ruthenium systems. Part 3. Preparation and characterization of cationic dienehydridotris(phosphine)ruthenium complexes: the crystal and molecular structure of (η-buta-1,3-diene)tris(dimethylphenylphosphine)hydridoruthenium(II) hexafluorophosphate
Autor: Michael Laing, Lynn Pope, Eric Singleton, Terence V. Ashworth
Publikováno v: J. Chem. Soc., Dalton Trans.. :1032-1036
The stable salts [RuH(diene)L3][PF6]{1; diene = cyclo-octa-1,5-diene (cod), hexa-1,3-diene, or buta-1,3-diene, L = PMe2Ph; diene = cod, L = P(OMe)3, P[(OCH2)3CMe], PPh2(OMe), PMe3, or PMePh2} have been prepared from the salt [RuH(cod)(NH2NMe2)3][PF6]
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c726f5beeac761201442a655096c8ddc
https://doi.org/10.1039/dt9780001032
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