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Autor:
Terence C. Morrill, Anvar U. Buranov
Publikováno v:
Tetrahedron Letters. 44:6301-6304
RhCl3-promoted hydroboration–oxidation reactions of representative alkenyl nitriles have been carried out. Carbanion of acetonitrile is formed from the carboncarbon heterolytic bond breaking in allyl cyanide during hydroboration. An unexpected p
Publikováno v:
Organometallics. 22:1626-1629
We find that alkenes isomerize rapidly in the presence of catalytic amounts of a hydroborating reagent and a rhodium compound. The hydroborating reagent is apparently responsible for the in situ generation of a metal hydride species, which has been i
Autor:
Gerald A. Takacs, J. Langston, K. S. V. Santhanam, Pulickel M. Ajayan, M. Croston, Terence C. Morrill, Massoud J Miri
Publikováno v:
International Journal of Nanoscience. :285-293
Aniline is oxidized to nitrosobenzene as the initial product, which undergoes further oxidation to nitrobenzene. The nitrosobenzene formation is catalyzed by functionalized multiwalled carbon nanotubes (CNT) followed by a coupling reaction between ni
Autor:
John P. Neenan, Sumittada M. Opitz, Michael A. Ussery, Charles L. Cooke, Terence C. Morrill, Linda M. Eckel
Publikováno v:
Bioorganic & Medicinal Chemistry Letters. 6:1381-1386
Selective borohydride reduction of adenosine dialdehyde ( 1 ) gave the known adenosine 2′-monoaldehyde ( 2 ). Reaction of 1 with N,N′-diphenylethylenediamine, followed by reduction and deblocking gave adenosine 3′-monoaldehyde ( 5 ), a new comp
Publikováno v:
Synthesis. 1993:973-976
Transmercuration of tri-exo-2-norbornylborane followed by chlorinolysis of the resultant organoborane is a low yield (≤5%) method of producing exo-2-norbornyl chloride. The primary source of this low yield is the inefficient transmercuration of the
Publikováno v:
ChemInform. 25
Transmercuration of tri-exo-2-norbornylborane followed by chlorinolysis of the resultant organoborane is a low yield (≤5%) method of producing exo-2-norbornyl chloride. The primary source of this low yield is the inefficient transmercuration of the
Publikováno v:
ChemInform. 27
Publikováno v:
The Journal of organic chemistry. 67(8)
When hydroboration of 1-octene is carried out in the presence of catalytic amounts of rhodium trichloride followed by the usual oxidation (hydrogen peroxide in aqueous alkali), only minor proportions of 1-octanol (2.4%) are formed accompanied by very
Publikováno v:
Main Group Metal Chemistry. 17