Zobrazeno 1 - 10
of 57
pro vyhledávání: '"Teng-Teng Chen"'
Autor:
Wei-Jia Chen, Teng-Teng Chen, Qiang Chen, Hai-Gang Lu, Xiao-Yun Zhao, Yuan-Yuan Ma, Qiao-Qiao Yan, Rui-Nan Yuan, Si-Dian Li, Lai-Sheng Wang
Publikováno v:
Communications Chemistry, Vol 5, Iss 1, Pp 1-7 (2022)
Despite its electron deficiency, boron can form multiple bonds with a variety of elements, but such bonds between boron and main-group metal elements are relatively rare. Here, the authors characterize boron–lead multiple bonds in PbB2O- and PbB3O2
Externí odkaz:
https://doaj.org/article/631657c63f734dc292a10d8d4a30f8cd
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
The most common oxidation state for lanthanides is +3. Here the authors use photoelectron spectroscopy and theoretical calculations to study half-sandwich complexes where a lanthanide center in the oxidation state +1 is bound to an aromatic wheel-lik
Externí odkaz:
https://doaj.org/article/8ffb2b68e0c44a80a5ea6bc0c54b1479
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
Borospherenes are the boron-based analogs of fullerene cages. Here, the authors report a class of Ln3B18 – metallo-borospherenes with unusual spherical trihedron geometry, in which the lanthanide atoms surprisingly form a part of the cage surface.
Externí odkaz:
https://doaj.org/article/969367a6842d4322887086a2f9b1488f
Autor:
Teng-Teng Chen1, Du, Matthew1, Zimo Yang2, Joel Yuen-Zhou1 joelyuen@ucsd.edu, Wei Xiong1,2,3 w2xiong@ucsd.edu
Publikováno v:
Science. 11/18/2022, Vol. 378 Issue 6621, p790-794. 5p. 3 Color Photographs.
Autor:
Zhen-Ling Wang, Teng-Teng Chen, Wei-Jia Chen, Wan-Lu Li, Jing Zhao, Xue-Lian Jiang, Jun Li, Lai-Sheng Wang, Han-Shi Hu
Publikováno v:
Chemical Science. 13:10082-10094
We report the smallest 4f-metalla-aromatic molecule of PrB2− exhibiting σ and π double aromaticity and multiple Pr–B bond characters.
Publikováno v:
The Journal of Physical Chemistry A. 125:2622-2630
Inverse-sandwich structures have been observed recently for dilanthanide boride clusters, in which two Ln atoms sandwich a monocyclic Bx ring for x = 7-9. An interesting question is if larger Bx rings are possible to form such inverse-sandwich cluste
Autor:
Si-Dian Li, Mei-Zhen Ao, Xinxin Tian, Yuan-Yuan Ma, Lai-Sheng Wang, Daofu Yuan, Qiang Chen, Teng-Teng Chen, Yue-Wen Mu, Wei-Jia Chen
Publikováno v:
Nanoscale. 13:3868-3876
Size-selected negatively-charged boron clusters (Bn−) have been found to be planar or quasi-planar in a wide size range. Even though cage structures emerged as the global minimum at B39−, the global minimum of B40− was in fact planar. Only in t
Autor:
Hua-Jin Zhai, Wei-Jia Chen, Teng-Teng Chen, Rui Li, Qiang Chen, Zhihong Wei, Si-Dian Li, Wen-Juan Tian, Lai-Sheng Wang, Miao Yan
Publikováno v:
Chemical Science. 12:8157-8164
Boron displays many unusual structural and bonding properties due to its electron deficiency. Here we show that a boron atom in a boron monoxide cluster (B9O−) exhibits transition-metal-like properties. Temperature-dependent photoelectron spectrosc
Publikováno v:
Annual review of physical chemistry. 73
Photoelectron spectroscopy combined with quantum chemistry has been a powerful approach to elucidate the structures and bonding of size-selected boron clusters (B n−), revealing a prevalent planar world that laid the foundation for borophenes. Inve
Publikováno v:
Angewandte Chemie International Edition. 59:15260-15265
Multiple bonds between boron and transition metals are known in many borylene (:BR) complexes via metal dπ →BR back-donation, despite the electron deficiency of boron. An electron-precise metal-boron triple bond was first observed in BiB2 O- [Bi